Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

15. Analytical Techniques:IR, NMR, Mass Spect

1H NMR:Spin-Splitting (N + 1) Rule

Organic Chemistry

15. Analytical Techniques:IR, NMR, Mass Spect

1H NMR:Spin-Splitting (N + 1) Rule

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6:43 minutes

Problem 28i

Textbook Question

Describe the ¹H NMR spectrum you would expect for each of the following compounds, indicating the relative positions of the signals:
i.

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Analyze the structure of the compound: The molecule is 1-bromo-2-bromopropane. It contains two bromine atoms attached to a propane backbone. The structure has three types of hydrogen environments due to the symmetry and substitution pattern.

Identify the distinct hydrogen environments: (1) The CH3 group at the end of the chain, (2) The CH group attached to the bromine atom, and (3) The CH2 group adjacent to the second bromine atom.

Predict the chemical shifts: (1) The CH3 group hydrogens will appear upfield (low ppm) due to their electron-rich environment, typically around 0.9-1.2 ppm. (2) The CH group hydrogens attached to the bromine will appear downfield (higher ppm) due to the electron-withdrawing effect of bromine, likely around 3.5-4.0 ppm. (3) The CH2 group hydrogens adjacent to the bromine will also appear downfield, but slightly less than the CH group, likely around 2.5-3.0 ppm.

Determine the splitting patterns: (1) The CH3 group hydrogens will be split into a doublet due to coupling with the adjacent CH group. (2) The CH group hydrogen will be split into a quartet due to coupling with the CH3 group and the CH2 group. (3) The CH2 group hydrogens will be split into a triplet due to coupling with the CH group.

Summarize the expected 1H NMR spectrum: The spectrum will show three distinct signals corresponding to the CH3, CH, and CH2 groups. The relative integration will be 3:1:2, reflecting the number of hydrogens in each environment. The chemical shifts and splitting patterns will help identify the structure of the compound.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

1H NMR Spectroscopy

1H NMR (Proton Nuclear Magnetic Resonance) spectroscopy is a powerful analytical technique used to determine the structure of organic compounds. It provides information about the number of hydrogen atoms in different environments within a molecule, allowing chemists to infer connectivity and functional groups. The resulting spectrum displays peaks corresponding to different hydrogen environments, with their chemical shifts indicating the electronic environment around each hydrogen.

Chemical Shift

Chemical shift refers to the position of a signal in an NMR spectrum, measured in parts per million (ppm). It is influenced by the electronic environment surrounding the hydrogen atoms; for example, hydrogen atoms attached to electronegative atoms (like bromine) will resonate at lower fields (higher ppm) due to deshielding effects. Understanding chemical shifts is crucial for predicting where signals will appear in the spectrum, which aids in identifying the structure of the compound.

Integration and Multiplicity

Integration in 1H NMR refers to the area under each peak, which correlates to the number of hydrogen atoms contributing to that signal. Multiplicity indicates the splitting pattern of the peaks, which arises from neighboring hydrogen atoms (n+1 rule). For example, a singlet indicates no neighboring hydrogens, while a doublet or triplet suggests one or two neighboring hydrogens, respectively. Together, integration and multiplicity provide insights into the hydrogen environment and connectivity within the molecule.

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