Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

15. Analytical Techniques:IR, NMR, Mass Spect

1H NMR:Spin-Splitting (N + 1) Rule

Organic Chemistry

15. Analytical Techniques:IR, NMR, Mass Spect

1H NMR:Spin-Splitting (N + 1) Rule

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Multiple Choice

Which of the following compounds gives a 1H NMR spectrum consisting of only a singlet, a triplet, and a pentet?

CH₃OCH₂CH₂CH₂CH₂OH

CH₃OCH₂CH₂OCH₂CH₃

CH₃OCH₂CH₂CH₂OCH₃

CH₃OCH₂CH₂OCH₃

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Verified step by step guidance

Identify the number of unique hydrogen environments in each compound. This is crucial because each unique environment corresponds to a different signal in the 1H NMR spectrum.

For the compound CH3OCH2CH2CH2CH2OH, analyze the structure: the terminal CH3 group, the CH2 groups in the chain, and the OH group. Count the unique hydrogen environments.

For the compound CH3OCH2CH2OCH2CH3, consider the symmetry and the different groups: the CH3 groups attached to oxygen, the CH2 groups between the oxygens, and the CH2 groups adjacent to the CH3 groups. Count the unique hydrogen environments.

For the compound CH3OCH2CH2CH2OCH3, note the symmetry: the CH3 groups attached to oxygen and the CH2 groups in the chain. Count the unique hydrogen environments.

Determine which compound has three unique hydrogen environments that would correspond to a singlet, a triplet, and a pentet in the 1H NMR spectrum. This involves understanding the splitting patterns based on the n+1 rule, where n is the number of neighboring hydrogens.