Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

4. Alkanes and Cycloalkanes

Cis vs Trans

Organic Chemistry

4. Alkanes and Cycloalkanes

Cis vs Trans

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6:40 minutes

Problem 11c

Textbook Question

Name the following alkenes, being sure to specify whether they are cis or trans.
(c)

Verified step by step guidance

Step 1: Identify the longest continuous carbon chain that contains the double bond. This will serve as the parent chain, and its name will be based on the number of carbons in the chain (e.g., ethene, propene, butene, etc.).

Step 2: Number the carbon atoms in the parent chain starting from the end closest to the double bond. This ensures the double bond gets the lowest possible number.

Step 3: Determine the position of the double bond by noting the number of the first carbon involved in the double bond. Include this number in the name of the alkene (e.g., 2-butene).

Step 4: Analyze the substituents attached to the double bond. If the two substituents on each carbon of the double bond are on the same side, the alkene is 'cis'; if they are on opposite sides, the alkene is 'trans'.

Step 5: Combine the information into the full name of the alkene, including the cis/trans designation, the position of the double bond, and the name of the parent chain.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Alkene Nomenclature

Alkenes are hydrocarbons that contain at least one carbon-carbon double bond. When naming alkenes, the longest carbon chain containing the double bond is identified, and the position of the double bond is indicated by the lowest possible number. The suffix '-ene' is used to denote the presence of the double bond, and substituents are named and numbered accordingly.

Cis-Trans Isomerism

Cis-trans isomerism, also known as geometric isomerism, occurs in alkenes due to the restricted rotation around the double bond. In cis isomers, substituents are on the same side of the double bond, while in trans isomers, they are on opposite sides. This spatial arrangement can significantly affect the physical and chemical properties of the compounds.

Priority Rules for Substituents

To determine whether an alkene is cis or trans, it is essential to apply priority rules to the substituents attached to the double-bonded carbons. The Cahn-Ingold-Prelog priority rules assign higher priority to substituents based on atomic number and connectivity. This helps in identifying the configuration of the alkene, ensuring accurate naming and classification.

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