Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

2. Molecular Representations

Intermolecular Forces

Organic Chemistry

2. Molecular Representations

Intermolecular Forces

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Multiple Choice

PRACTICE:Which of the following pairs of molecules would have the highest boiling point?

Compound on the left

Compound on the right

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Verified step by step guidance

Identify the two compounds: The compound on the left is cyclohexane, a cyclic alkane with the formula C6H12. The compound on the right is hexane, a straight-chain alkane with the formula C6H14.

Understand the factors affecting boiling points: Boiling points are influenced by molecular weight, molecular structure, and intermolecular forces. In general, stronger intermolecular forces result in higher boiling points.

Compare the molecular structures: Cyclohexane is a cyclic structure, which can lead to different packing and intermolecular interactions compared to the linear structure of hexane.

Consider the types of intermolecular forces: Both cyclohexane and hexane are nonpolar molecules, so the primary intermolecular force is London dispersion forces. The shape and surface area of the molecules can affect the strength of these forces.

Evaluate the boiling points based on structure: Cyclic structures like cyclohexane often have higher boiling points than their straight-chain counterparts due to more effective packing and stronger dispersion forces. Therefore, cyclohexane is expected to have a higher boiling point than hexane.