Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

35. Transition Metals

Catalytic Allylic Alkylation

Organic Chemistry

35. Transition Metals

Catalytic Allylic Alkylation

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Multiple Choice

Predict the structures of organopalladium compound A and coupling product B in the following reaction sequence.

Structures of organopalladium compound A and coupling product B for the reaction.

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Verified step by step guidance

Identify the starting material: The compound is a cycloalkene with an acetate leaving group. The acetate group is positioned on a carbon adjacent to the double bond.

Understand the role of Pd(PPh3)4: This is a palladium catalyst used in cross-coupling reactions. It will facilitate the formation of an organopalladium intermediate by oxidative addition.

Predict the structure of compound A: The acetate group will leave, and the palladium catalyst will form a bond with the carbon that was attached to the acetate, creating an organopalladium species.

Consider the reaction with the diester: The organopalladium compound A will undergo a nucleophilic attack on the diester, facilitated by the base NaOEt, leading to the formation of a new carbon-carbon bond.

Predict the structure of compound B: The final product will be a cycloalkene with the diester moiety attached at the position where the palladium was initially bonded, completing the coupling reaction.