Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

16. Conjugated Systems

Cope Rearrangement

Organic Chemistry

16. Conjugated Systems

Cope Rearrangement

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Multiple Choice

Provide the mechanism and final product for the following reaction

Octagonal structure representing a cyclic compound in organic chemistry.

Pentagonal structure illustrating a cyclic compound in organic chemistry.

Another octagonal structure depicting a cyclic compound in organic chemistry.

Another pentagonal structure showing a cyclic compound in organic chemistry.

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Verified step by step guidance

Identify the reaction type: The reaction involves a cycloaddition, specifically a Diels-Alder reaction, which is a [4+2] cycloaddition between a diene and a dienophile.

Analyze the reactants: The diene is a conjugated system with two double bonds, and the dienophile is a molecule with a triple bond, which can participate in the cycloaddition.

Consider the reaction conditions: The presence of heat (Δ) suggests that the reaction is thermally driven, which is typical for Diels-Alder reactions.

Predict the mechanism: The diene will undergo a concerted reaction with the dienophile, forming a new six-membered ring. The pi electrons from the diene and the dienophile will rearrange to form new sigma bonds.

Determine the final product: The result of the cycloaddition will be a cyclohexene derivative, where the new ring is formed by the joining of the diene and the dienophile, with the triple bond of the dienophile becoming a double bond in the product.