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Multiple Choice
Which of the following statements about the acidity of carboxylic acids is most likely true?
A
Carboxylic acids are generally weaker acids than alcohols.
B
Carboxylic acids do not dissociate in water.
C
Carboxylic acids are stronger acids than phenols.
D
Carboxylic acids have a higher pH than amines.
Verified step by step guidance
1
Understand the basic structure of carboxylic acids, which contain a carboxyl group (COOH). This group is responsible for their acidic properties.
Recall that acidity is determined by the ability of a compound to donate a proton (H+). Carboxylic acids can donate a proton from the hydroxyl group (OH) in the carboxyl group.
Compare the acidity of carboxylic acids with other organic compounds. Carboxylic acids are generally stronger acids than alcohols and phenols due to the resonance stabilization of their conjugate base (carboxylate ion).
Consider the dissociation of carboxylic acids in water. They do dissociate to some extent, releasing H+ ions, which makes them acidic in aqueous solutions.
Evaluate the pH comparison: Carboxylic acids typically have a lower pH (more acidic) than amines, which are basic compounds. This is due to the presence of the carboxyl group, which can release protons, lowering the pH.