Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

3. Acids and Bases

Organic Chemistry Reactions

Organic Chemistry

3. Acids and Bases

Organic Chemistry Reactions

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Multiple Choice

Which of the following statements about Grignard reagents is true?

Grignard reagents are stable in the presence of water.

Grignard reagents are formed by the reaction of an alkyl halide with magnesium in dry ether.

Grignard reagents can be used to form alkenes by reacting with carbon dioxide.

Grignard reagents are typically used in acidic conditions to form alcohols.

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Verified step by step guidance

Begin by understanding what Grignard reagents are. Grignard reagents are organomagnesium compounds typically represented as RMgX, where R is an alkyl or aryl group and X is a halogen.

Recognize the conditions required for the formation of Grignard reagents. They are formed by the reaction of an alkyl halide with magnesium metal in anhydrous (dry) ether. This is crucial because Grignard reagents are highly reactive with water.

Consider the reactivity of Grignard reagents. They are very sensitive to moisture and react with water to form hydrocarbons, thus they are not stable in the presence of water.

Evaluate the use of Grignard reagents in synthesis. They are commonly used to form alcohols by reacting with carbonyl compounds, not typically in acidic conditions, as acids would protonate the Grignard reagent, rendering it inactive.

Understand the reaction of Grignard reagents with carbon dioxide. When Grignard reagents react with CO₂, they form carboxylic acids, not alkenes. This is an important synthetic application of Grignard reagents.