Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

4. Alkanes and Cycloalkanes

Naming Bicyclic Compounds

Organic Chemistry

4. Alkanes and Cycloalkanes

Naming Bicyclic Compounds

Previous problemNext problem

7:26 minutes

Problem 31a,b

Textbook Question

Name the following compounds.
(a)
(b)

Verified step by step guidance

Step 1: Analyze the structure in part (a). The compound consists of a bicyclic system with two fused rings. Count the number of carbons in each ring and identify the bridgehead carbons.

Step 2: Determine the number of carbons in the bridge connecting the two rings in part (a). Use the bicyclo nomenclature format: bicyclo[x.y.z]alkane, where x, y, and z represent the number of carbons in the bridges.

Step 3: For part (b), observe the structure. It is a bicyclic compound with a spiro junction. Count the number of carbons in each ring connected at the spiro center.

Step 4: Use the spiro nomenclature format for part (b): spiro[x.y]alkane, where x and y represent the number of carbons in the two rings excluding the spiro carbon.

Step 5: Combine the structural analysis with the appropriate IUPAC naming conventions to name both compounds systematically.

Verified video answer for a similar problem:

This video solution was recommended by our tutors as helpful for the problem above

Video duration:

Play a video:

Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Nomenclature of Organic Compounds

Nomenclature refers to the systematic naming of organic compounds based on established rules, primarily those set by the International Union of Pure and Applied Chemistry (IUPAC). This involves identifying the longest carbon chain, determining the functional groups present, and applying prefixes and suffixes to convey the structure and characteristics of the compound.

Cycloalkanes

Cycloalkanes are a class of hydrocarbons characterized by carbon atoms arranged in a ring structure. They are saturated compounds, meaning they contain only single bonds between carbon atoms. The simplest cycloalkane is cyclopropane, which consists of three carbon atoms in a ring, while larger cycloalkanes can have more complex structures and varying degrees of stability.

Stereochemistry

Stereochemistry is the study of the spatial arrangement of atoms in molecules and how this affects their chemical behavior. In organic chemistry, stereochemistry is crucial for understanding isomerism, where compounds with the same molecular formula can have different structures or orientations, leading to different properties and reactivities. This concept is particularly important when naming compounds that may have chiral centers.

Watch next

Master The two types of bicyclic molecules with a bite sized video explanation from Johnny

Start learning