Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

17. Ultraviolet Spectroscopy

Woodward-Fieser Rules

Organic Chemistry

17. Ultraviolet Spectroscopy

Woodward-Fieser Rules

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Multiple Choice

Using the Woodward-Fieser Rules, determine the λ_max for the following compound.

239 nm

326 nm

390 nm

268 nm

235 nm

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Verified step by step guidance

Identify the base structure of the compound. In this case, the compound is a bicyclic diene system, which is a type of conjugated diene.

Apply the Woodward-Fieser rules for conjugated dienes. The base value for an acyclic diene is 214 nm. For a homoannular diene, the base value is 253 nm.

Count the number of alkyl substituents and exocyclic double bonds. Each alkyl substituent adds 5 nm, and each exocyclic double bond adds 5 nm to the base value.

Identify any additional conjugation or auxochromes that might affect the λmax. In this structure, consider the effect of the bicyclic system and any additional conjugation.

Sum the contributions from the base value, substituents, and any other factors to estimate the λmax for the compound. Compare this calculated value to the given options to determine the most likely λmax.