Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

12. Alcohols, Ethers, Epoxides and Thiols

Leaving Group Conversions - SOCl2 and PBr3

Organic Chemistry

12. Alcohols, Ethers, Epoxides and Thiols

Leaving Group Conversions - SOCl2 and PBr3

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4:28 minutes

Problem 97c

Textbook Question

Suggest the appropriate reagents to carry out the following transformations.
(c)

Verified step by step guidance

Identify the functional groups present in the starting material and the desired product. This will help determine the type of reaction needed for the transformation.

Consider the type of reaction that can convert the starting material into the desired product. Common transformations include oxidation, reduction, substitution, addition, and elimination reactions.

Select the appropriate reagents based on the type of reaction identified. For example, if the transformation involves oxidation, reagents like

KMnO_4

CrO_3

might be suitable.

Consider the reaction conditions such as temperature, solvent, and pH, which can influence the choice of reagents and the success of the transformation.

Verify the mechanism of the reaction to ensure that the chosen reagents will lead to the desired product without unwanted side reactions or by-products.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Functional Group Transformation

Functional group transformation involves converting one functional group into another, which is a fundamental aspect of organic synthesis. Understanding the reactivity and compatibility of different functional groups is crucial for selecting the appropriate reagents and conditions to achieve the desired transformation.

Reagent Selection

Reagent selection is the process of choosing the correct chemical substances to facilitate a specific chemical reaction. This involves understanding the mechanism of the reaction, the stability of intermediates, and the compatibility of reagents with the starting materials and desired products.

Reaction Mechanism

A reaction mechanism is a step-by-step description of the process by which reactants are converted into products. It includes the breaking and forming of bonds, the role of catalysts, and the identification of intermediates. Understanding the mechanism helps in predicting the outcome of a reaction and in troubleshooting any issues that arise during the transformation.

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Related Practice

Textbook Question

Suggest the appropriate reagents to carry out the following transformations.

(g)

Textbook Question

Draw structures for compounds A–F.

Textbook Question

What is the product of each of the following reactions?

Textbook Question

Suggest the appropriate reagents to carry out the following transformations.

(b)

Textbook Question

Predict the product(s) that would result when molecules (a)–(p) are allowed to react under the following conditions: (iii) SOCl₂ , NEt₃. If no reaction occurs, write 'no reaction.'

(a)

Multiple Choice

Predict the major, organic product for the following reaction.

Textbook Question

Write balanced equations for the three preceding reactions.

Textbook Question

Two products are observed in the following reaction.

a. Suggest a mechanism to explain how these two products are formed.

b. Your mechanism for part (a) should be different from the usual mechanism of the reaction of SOCl₂ with alcohols. Explain why the reaction follows a different mechanism in this case.

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Suggest the appropriate reagents to carry out the following transformations. (c)

Key Concepts

Functional Group Transformation

Reagent Selection

Reaction Mechanism

Watch next

Suggest the appropriate reagents to carry out the following transformations.
(c)