Table of contents

1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

36. Synthetic Polymers

Chain-Growth Polymers

Organic Chemistry

36. Synthetic Polymers

Chain-Growth Polymers

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Multiple Choice

Which of the following monomers will show the greatest selectivity for head-to-tail addition?

prop-1-ene

(E)-but-2-ene

2-methylprop-1-ene

None of these.

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Verified step by step guidance

Identify the structure of each monomer: prop-1-ene, (E)-but-2-ene, and 2-methylprop-1-ene. Note the position of the double bond and any substituents attached to the carbon atoms involved in the double bond.

Understand the concept of head-to-tail addition in polymer chemistry, where the head of one monomer (the more substituted end of the double bond) reacts with the tail of another monomer (the less substituted end).

Analyze the substituents on the double-bonded carbons for each monomer. The greater the difference in substitution between the two carbons, the more selective the monomer will be for head-to-tail addition.

For prop-1-ene, the double bond is between a primary and a secondary carbon. For (E)-but-2-ene, the double bond is between two secondary carbons. For 2-methylprop-1-ene, the double bond is between a tertiary and a primary carbon.

Determine which monomer has the greatest difference in substitution between the two carbons of the double bond. 2-methylprop-1-ene, with a tertiary and a primary carbon, will show the greatest selectivity for head-to-tail addition due to the significant difference in substitution.