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1. A Review of General Chemistry5h 5m
2. Molecular Representations1h 14m
3. Acids and Bases2h 46m
4. Alkanes and Cycloalkanes4h 17m
5. Chirality3h 39m
6. Thermodynamics and Kinetics1h 22m
7. Substitution Reactions1h 48m
8. Elimination Reactions2h 30m
9. Alkenes and Alkynes2h 9m
10. Addition Reactions3h 19m
11. Radical Reactions1h 58m
12. Alcohols, Ethers, Epoxides and Thiols2h 42m
13. Alcohols and Carbonyl Compounds2h 17m
14. Synthetic Techniques1h 26m
15. Analytical Techniques:IR, NMR, Mass Spect7h 3m
16. Conjugated Systems6h 13m
17. Ultraviolet Spectroscopy51m
18. Aromaticity2h 34m
19. Reactions of Aromatics: EAS and Beyond5h 1m
20. Phenols55m
21. Aldehydes and Ketones: Nucleophilic Addition4h 56m
22. Carboxylic Acid Derivatives: NAS2h 51m
23. The Chemistry of Thioesters, Phophate Ester and Phosphate Anhydrides1h 10m
24. Enolate Chemistry: Reactions at the Alpha-Carbon1h 53m
25. Condensation Chemistry2h 9m
26. Amines1h 43m
27. Heterocycles2h 0m
28. Carbohydrates5h 53m
29. Amino Acids4h 20m
30. Peptides and Proteins2h 42m
31. Catalysis in Organic Reactions1h 30m
32. Lipids 2h 50m
33. The Organic Chemistry of Metabolic Pathways2h 52m
34. Nucleic Acids1h 32m
35. Transition Metals6h 14m
36. Synthetic Polymers1h 49m

35. Transition Metals

Cross-Coupling General Reactions

Organic Chemistry

35. Transition Metals

Cross-Coupling General Reactions

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Multiple Choice

What are the three stjpg of a transition metal-catalyzed coupling reaction?

Oxidative addition, transmetallation, reductive elimination.

Initiation, propagation, termination

Electrophilic addition, carbocation rearrangement, nucleophilic elimination.

Nucleophilic addition, proton transfer, electrophilic elimination

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Verified step by step guidance

Understand the concept of transition metal-catalyzed coupling reactions, which are important in forming carbon-carbon bonds in organic synthesis.

Identify the three key stages of a typical transition metal-catalyzed coupling reaction: oxidative addition, transmetallation, and reductive elimination.

Oxidative addition involves the insertion of a transition metal into a bond, typically a carbon-halogen bond, resulting in the formation of a metal complex.

Transmetallation is the process where a ligand is transferred from one metal to another, often involving the exchange of organic groups between the metal complex and an organometallic reagent.

Reductive elimination is the final step where the metal complex releases the coupled product, regenerating the transition metal catalyst in its original oxidation state.