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Multiple Choice
Which of the following statements about enantiomers is true?
A
Enantiomers can be separated by simple distillation.
B
Enantiomers are mirror images that are superimposable.
C
Enantiomers have identical physical properties except for their interaction with plane-polarized light.
D
Enantiomers have different chemical properties in achiral environments.
Verified step by step guidance
1
Understand the concept of enantiomers: Enantiomers are a type of stereoisomer that are non-superimposable mirror images of each other. This means that they have the same molecular formula and connectivity but differ in spatial arrangement.
Consider the physical properties of enantiomers: Enantiomers have identical physical properties such as boiling point, melting point, and solubility. However, they differ in how they interact with plane-polarized light, a property known as optical activity.
Evaluate the separation methods: Enantiomers cannot be separated by simple distillation because they have identical boiling points. Separation typically requires chiral resolution techniques, such as using a chiral stationary phase in chromatography.
Assess the chemical properties in achiral environments: In achiral environments, enantiomers generally exhibit identical chemical properties. However, they may behave differently in chiral environments, such as biological systems.
Identify the correct statement: Based on the understanding of enantiomers, the statement 'Enantiomers have identical physical properties except for their interaction with plane-polarized light' is true, as this highlights their unique optical activity.