cis-3,4-Dimethylcyclobutene undergoes thermal ring opening to form the two products shown. One of the products is formed in 99% yield, the other in 1% yield. Which is which?

Draw the product of each of the following reactions:

d.

Draw the product of each of the following reactions:

e.

Draw the product of each of the following reactions:

f.

Explain why two different products are formed from disrotatory ring closure of (2E,4Z,6Z)-octatriene, but only one product is formed from disrotatory ring closure of (2E,4Z,6E)-octatriene.

If isomer A is heated to about 100 °C, a mixture of isomers A and B is formed. Explain why there is no trace of isomer C or D.

b. What would be the product if trans-2-butene were used instead of ethene?

Predict the product of the following electrocyclic reactions.

(a)

Draw the products you’d expect to form in Assessment 22.38.

(c)