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Multiple Choice
Which of the following statements about aqueous solutions is/are true?
A
For an basic solution the concentration of H3O+ is greater than the concentration of OH-.
B
The pH of a neutral aqueous solution is 7.00 at all temperatures.
C
An acidic solution under normal conditions has a pH value less than 7.00.
D
If the concentration of H3O+ decreases then the concentration of OH- will also decrease.
E
The pH of aqueous solutions is less than 7.
Verified step by step guidance
1
Understand the nature of aqueous solutions: Aqueous solutions are those where water is the solvent. The pH scale is used to determine the acidity or basicity of a solution, with 7 being neutral, below 7 acidic, and above 7 basic.
Analyze the first statement: 'For a basic solution, the concentration of H3O+ is greater than the concentration of OH-.' In a basic solution, the concentration of OH- is actually greater than that of H3O+, so this statement is false.
Evaluate the second statement: 'The pH of a neutral aqueous solution is 7.00 at all temperatures.' This is incorrect because the pH of pure water is 7.00 only at 25°C. At other temperatures, the pH can vary slightly due to changes in the ionization of water.
Consider the third statement: 'An acidic solution under normal conditions has a pH value less than 7.00.' This statement is true, as acidic solutions have a higher concentration of H3O+ ions, resulting in a pH less than 7.
Examine the fourth statement: 'If the concentration of H3O+ decreases then the concentration of OH- will also decrease.' This is false because, according to the water ion product (Kw), if the concentration of H3O+ decreases, the concentration of OH- must increase to maintain the constant value of Kw at a given temperature.