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Multiple Choice
Calculate the ∆Hrxn for Given the following reactions:
A
-177.85 kJ
B
-355.73 kJ
C
-258.36 kJ
D
-487.27 kJ
Verified step by step guidance
1
Identify the target reaction: ClF (g) + F2 (g) → ClF3 (g). We need to find the ΔHrxn for this reaction using the given reactions.
Use Hess's Law, which states that the total enthalpy change for a reaction is the sum of the enthalpy changes for each step of the reaction. We will manipulate the given reactions to achieve the target reaction.
Reverse the second given reaction: 2 Cl2O (g) + 6 F2O (g) → 4 ClF3 (g) + 4 O2 (g). This changes the sign of ΔH° to -682.8 kJ.
Multiply the third given reaction by 3/2 to match the stoichiometry of F2 in the target reaction: 3 F2 (g) + 3/2 O2 (g) → 3 F2O (g). This scales the ΔHrxn to -272.55 kJ.
Combine the modified reactions to cancel out intermediates and obtain the target reaction. Sum the ΔH values of the modified reactions to find the ΔHrxn for the target reaction.