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Multiple Choice
Cellulose, an unbranched β(1-4)-linked homopolysaccharide of D-glucose, differs from starch in that starch is:
A
A β-1,6-linked D-mannose homopolysaccharide that is branched.
B
A β-1,6-linked D-glucose homopolysaccharide that is unbranched.
C
An α-1,6-linked D-glucose homopolysaccharide that can be branched or unbranched.
D
An α-1,4-linked D-glucose homopolysaccharide that can be branched or unbranched.
E
An α-1,4-linked D-mannose homopolysaccharide that is branched.
Verified step by step guidance
1
Understand the structure of cellulose: Cellulose is a homopolysaccharide composed of D-glucose units linked by β(1-4) glycosidic bonds. It is unbranched.
Recognize the structure of starch: Starch is a polysaccharide composed of D-glucose units. It can be either amylose, which is unbranched, or amylopectin, which is branched.
Identify the type of glycosidic linkage in starch: Starch primarily consists of α(1-4) glycosidic linkages in amylose and both α(1-4) and α(1-6) linkages in amylopectin, where the α(1-6) linkages create branches.
Compare the linkages: Cellulose has β(1-4) linkages, while starch has α(1-4) linkages, with potential α(1-6) linkages for branching in amylopectin.
Conclude the correct description of starch: Starch is an α-1,4-linked D-glucose homopolysaccharide that can be branched (amylopectin) or unbranched (amylose).