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Multiple Choice
Calculate the initial reaction rate for A → B, given that [A] i = 9.6 M, [B] i = 0 & [A] f after 0.01 μsec = 9.14 mM.
A
46 M/s.
B
959 M/s.
C
9.59 x 108 M/s.
D
4.6 x 107 M/s.
Verified step by step guidance
1
Understand the concept of reaction rate: The initial reaction rate is the change in concentration of a reactant or product per unit time. It is typically expressed in molarity per second (M/s).
Convert units where necessary: Ensure all concentrations are in the same units. Here, [A] i is given in molarity (M) and [A] f is given in millimolar (mM). Convert [A] f from mM to M by dividing by 1000.
Calculate the change in concentration of A: Use the formula Δ[A] = [A] i - [A] f, where [A] i is the initial concentration and [A] f is the final concentration after the given time.
Determine the time interval: The time interval given is 0.01 μsec. Convert this to seconds by multiplying by 10^-6.
Calculate the initial reaction rate: Use the formula rate = Δ[A] / Δt, where Δ[A] is the change in concentration and Δt is the change in time. Substitute the values obtained from the previous steps to find the initial reaction rate.