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Multiple Choice
Which of these statements is false?
A
The Fehling's test allows us to detect the presence of reducing sugars.
B
The Benedict's test allows us to detect the presence of sugars with a free aldehyde or ketone group.
C
All simple, linear monosaccharides are reducing sugars.
D
All disaccharides have exposed carbonyl groups and are also reducing sugars.
E
Sucrose and other non-reducing sugars will not react with Tollens' solution.
Verified step by step guidance
1
Understand the concept of reducing sugars: Reducing sugars are carbohydrates that can donate electrons to another molecule, typically through their free aldehyde or ketone group. This property allows them to reduce certain chemical reagents, such as those used in Fehling's, Benedict's, and Tollens' tests.
Review the Fehling's test: Fehling's test is used to detect the presence of reducing sugars. It involves the reduction of copper(II) ions to copper(I) oxide, which forms a red precipitate. This test is positive for sugars with free aldehyde groups.
Examine the Benedict's test: Similar to Fehling's test, Benedict's test detects reducing sugars. It uses copper(II) sulfate in an alkaline solution, which is reduced to copper(I) oxide, forming a red precipitate. This test is positive for sugars with free aldehyde or ketone groups.
Consider the statement about monosaccharides: All simple, linear monosaccharides are reducing sugars because they have free aldehyde or ketone groups that can participate in redox reactions.
Evaluate the statement about disaccharides: Not all disaccharides are reducing sugars. For example, sucrose is a non-reducing sugar because its glycosidic bond involves the aldehyde group of glucose and the ketone group of fructose, preventing them from reacting with Tollens' solution or other similar reagents.