Predict the major products of the following reactions:

(d)

Draw structures of the following derivatives.

(a) the 2,4-dinitrophenylhydrazone of benzaldehyde

Draw structures of the following derivatives.

(b) the semicarbazone of cyclobutanone

Draw structures of the following derivatives.

(c) cyclopropanone oxime

Draw structures of the following derivatives.

(d) the ethylene acetal of hexan-3-one

Draw structures of the following derivatives.

(e) acetaldehyde dimethyl acetal

Draw structures of the following derivatives.

(f) the methyl hemiacetal of formaldehyde

Draw structures of the following derivatives.

(g) the (E) isomer of the ethyl imine of propiophenone

Draw structures of the following derivatives.

(h) the hemiacetal form of 5-hydroxypentanal

Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.

(b) CH₃(CH₂)₂CO(CH₂)₂CH₃

Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.

(c) CH₃(CH₂)₅CHO

Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.

(d) PhCOPh

Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.

(g) CH₃CH₂CHBrCH₂CH(CH₃)CHO

Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.

(h) Ph–CH=CH–CHO

Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.

(j)

Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.

(k)

Name the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.

(l)

Predict the major products of the following reactions.

(a)

Predict the major products of the following reactions.

(b)

Predict the major products of the following reactions.

(c)

Predict the major products of the following reactions.

(d)

Predict the major products of the following reactions.

(e)

Predict the major products of the following reactions.

(f)

Predict the major products of the following reactions.

(g)

Predict the major products of the following reactions.

(h)

Predict the major products of the following reactions.

(i)

Predict the major products of the following reactions.

(j)

Rank the following carbonyl compounds in order of increasing equilibrium constant for hydration:

CH₃COCH₂Cl ClCH₂CHO CH₂O CH₃COCH₃ CH₃CHO

Acetals can serve as protecting groups for 1,2-diols, as well as for aldehydes and ketones. When the acetal is formed from acetone plus the diol, the acetal is called an acetonide. Show the acetonides formed from these diols with acetone under acid catalysis.

Acetals can serve as protecting groups for 1,2-diols, as well as for aldehydes and ketones. When the acetal is formed from acetone plus the diol, the acetal is called an acetonide. Show the acetonides formed from these diols with acetone under acid catalysis.