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Bruice 8th EditionCh. 16 - Reactions of Aldehydes and Ketones More Reactions of Carboxylic Acid DerivativesProblem 50a
Using bromocyclohexane as a starting material, how could you synthesize the following compounds?
a.
Problem 50c
Using bromocyclohexane as a starting material, how could you synthesize the following compounds?
c.
Problem 50d
Using bromocyclohexane as a starting material, how could you synthesize the following compounds?
d.
Problem 51a
What is the major product of each of the following reactions?
a.
Problem 51b
What is the major product of each of the following reactions?
b.
Problem 51c,d
What is the major product of each of the following reactions?
c.
d.
Problem 52a
What is the major product of each of the following reactions?
a.
Problem 52b
What is the major product of each of the following reactions?
b.
Problem 54b
What are the products of the following reactions?
b.
Problem 54e
What are the products of the following reactions?
e.
Problem 54f
What are the products of the following reactions?
f.
Problem 54g
What are the products of the following reactions?
g.
Problem 54h
What are the products of the following reactions?
h.
Problem 55
Rank the following compounds from most reactive to least reactive toward nucleophilic addition:
Problem 56
Draw the structure of two esters that will be reduced to propanol and butanol by LiAlH4 (followed by addition of aqueous acid).
Problem 57a(1)
Show the reagents required to form the primary alcohol in each of the following reactions.
Problem 57a(3)
a. Show the reagents required to form the primary alcohol in each of the following reactions.
Problem 57a(4)
a. Show the reagents required to form the primary alcohol in each of the following reactions.
Problem 57a(5)
a. Show the reagents required to form the primary alcohol in each of the following reactions.
Problem 57a(7)
a. Show the reagents required to form the primary alcohol in each of the following reactions.
Problem 57a(8)
a. Show the reagents required to form the primary alcohol in each of the following reactions.
Problem 57a(10)
a. Show the reagents required to form the primary alcohol in each of the following reactions.
Problem 57b
Which of the reactions cannot be used for the synthesis of isobutyl alcohol?
Problem 58a,b,c
Draw the products of the following reactions. Indicate whether each reaction is an oxidation or a reduction.
a.
b.
c.
Problem 58d
Draw the products of the following reactions. Indicate whether each reaction is an oxidation or a reduction.
d.
Problem 58e
Draw the products of the following reactions. Indicate whether each reaction is an oxidation or a reduction.
e.
Problem 58f
Draw the products of the following reactions. Indicate whether each reaction is an oxidation or a reduction.
f.
Problem 60a,b
Using cyclohexanone as the starting material, describe how each of the following compounds can be synthesized:
a.
b.
Problem 60c
Using cyclohexanone as the starting material, describe how each of the following compounds can be synthesized:
c.
Problem 60d
Using cyclohexanone as the starting material, describe how each of the following compounds can be synthesized:
d.
