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Problem 52c
Show how you would synthesize the following derivatives from appropriate carbonyl compounds.
(c)
Problem 52d
Show how you would synthesize the following derivatives from appropriate carbonyl compounds.
(d)
Problem 53a
Predict the products formed when cyclohexanone reacts with the following reagents.
(a) CH3NH2, H+
Problem 53b
Predict the products formed when cyclohexanone reacts with the following reagents.
(b) excess CH3OH, H+
Problem 53c
Predict the products formed when cyclohexanone reacts with the following reagents.
(c) hydroxylamine and weak acid
Problem 53d
Predict the products formed when cyclohexanone reacts with the following reagents.
(d) ethylene glycol and p-toluenesulfonic acid
Problem 53e
Predict the products formed when cyclohexanone reacts with the following reagents.
(e) phenylhydrazine and weak acid
Problem 53f
Predict the products formed when cyclohexanone reacts with the following reagents.
(f) PhMgBr and then mild H3O+
Problem 53g
Predict the products formed when cyclohexanone reacts with the following reagents.
g. Tollens reagent
Problem 53h
Predict the products formed when cyclohexanone reacts with the following reagents.
(h) sodium acetylide, then mild H3O+
Problem 53i
Predict the products formed when cyclohexanone reacts with the following reagents.
(i) hydrazine, then hot, fused KOH
Problem 53k
Predict the products formed when cyclohexanone reacts with the following reagents.
(k) sodium cyanide
Problem 53l
Predict the products formed when cyclohexanone reacts with the following reagents.
(l) acidic hydrolysis of the product from (k)
Problem 54a
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
(a) PhMgBr, then H3O+
Problem 54b
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
b. Tollens reagent
Problem 54c
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
(c) semicarbazide and weak acid
Problem 54d
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
(d) excess ethanol and acid
Problem 54e
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
(e) propane-1,3-diol, H+
Problem 54f
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
(f) zinc amalgam and dilute hydrochloric acid
Problem 55a
Show how you would synthesize octan-2-one from each compound. You may use any necessary reagents.
(a) heptanal
Problem 55b
Show how you would synthesize octan-2-one from each compound. You may use any necessary reagents.
(b) oct-1-yne
Problem 55c
Show how you would synthesize octan-2-one from each compound. You may use any necessary reagents.
(c) 2,3-dimethylnon-2-ene
Problem 55e
Show how you would synthesize octan-2-one from each compound. You may use any necessary reagents.
(e) heptanoic acid
Problem 55f
Show how you would synthesize octan-2-one from each compound. You may use any necessary reagents.
(f) CH3(CH2)5CN
Problem 56a
Show how you would synthesize octanal from each compound. You may use any necessary reagents.
(a) octan-1-ol
Problem 56b
Show how you would synthesize octanal from each compound. You may use any necessary reagents.
(b) non-1-ene
Problem 56c
Show how you would synthesize octanal from each compound. You may use any necessary reagents.
(c) oct-1-yne
Problem 56d
Show how you would synthesize octanal from each compound. You may use any necessary reagents.
(d) 1-bromoheptane
Problem 56e
Show how you would synthesize octanal from each compound. You may use any necessary reagents.
(e) 1-bromohexane
Problem 56f
Show how you would synthesize octanal from each compound. You may use any necessary reagents.
(f) octanoic acid
