5. Chirality

Of the following pairs, identify the higher priority substituent according to the CIP rules. (R = position of attachment to the asymmetric center.)

(a)

Prioritize the substituents at each chiral center and then, by comparing them to the models you created in Section 6.3.2, label the absolute configuration as R or S.

(a)

Prioritize the substituents at each chiral center and then, by each of the two methods discussed in Section 6.3.2.4, determine the absolute configuration. [Do not use your models, except to check your answers.]

(c)

Prioritize the substituents at each chiral center and then, by each of the two methods discussed in Section 6.3.2.4, determine the absolute configuration. [Do not use your models, except to check your answers.]

(d)

Prioritize the substituents at each chiral center and then, by each of the two methods discussed in Section 6.3.2.4, determine the absolute configuration. [Do not use your models, except to check your answers.]

(h)

Complete the structure of each of these so that it matches the (R) or (S) configuration associated with the name.

(a)

Draw the structure that corresponds to the name provided.

(c) (2E,4S,6Z)-octa-2,6-dien-4-ol

Given the following names, draw the structure of the molecule.

c. (S)-2-methyloctan-4-amine

Given the name, draw the structure of the following compounds.

(b) (4Z,8R)-8-bromo-5-methylnon-4-ene

Given the name, draw the structure of the following compounds.

(e) (3R,5S)-5-chloro-3-isopropylcycloheptene

Using IUPAC rules, name the following molecules.

(c)

Using IUPAC rules, name the following molecules.

(e)

Name the following alkynes according to the IUPAC rules of nomenclature.

(b)

Complete the structure of each of these so that it matches the (R) or (S) configuration associated with the name.

(d)

Complete the structure of each of these so that it matches the (R) or (S) configuration associated with the name.

(e)