1. A Review of General Chemistry

Determine whether the following pairs of structures are actually different compounds or simply resonance forms of the same compounds.

e.

f.

g.

h.

Determine whether the following pairs of structures are actually different compounds or simply resonance forms of the same compounds.

i.

j.

k.

l.

Determine whether the following pairs of structures are actually different compounds or simply resonance forms of the same compounds.

a.

b.

c.

d.

The following compound can become protonated on any of the three nitrogen atoms. One of these nitrogens is much more basic than the others, however.

a. Draw the important resonance forms of the products of protonation on each of the three nitrogen atoms.

Two resonance structures are shown for each molecule. Use the arrow-pushing formalism to represent the electron flow from the structure on the left to the one on the right.

(e)

Each pair of structures represents two valid resonance structures. Use the arrow-pushing formalism to justify the formation of the one on the left from the one on the right.

(a)

Each pair of structures represents two valid resonance structures. Use the arrow-pushing formalism to justify the formation of the one on the left from the one on the right.

(b)

Draw the resonance structure that would result from the indicated movement of electrons.

(a)

For each of the molecules shown, do the following:

(i) Identify all pushable pairs.

(ii) Identify all places where electrons can be pushed.

(iii) Draw one valid resonance structure.

(a)

In the following molecules, identify all pushable electron pairs.

(a)

Two resonance structures are shown for each molecule. Use the arrow-pushing formalism to represent the electron flow from the structure on the left to the one on the right.

(b)

Two resonance structures are shown for each molecule. Use the arrow-pushing formalism to represent the electron flow from the structure on the left to the one on the right.

(d)

Two resonance structures are shown for each molecule. Use the arrow-pushing formalism to represent the electron flow from the structure on the left to the one on the right.

(f)

Identify the resonance structure that will be produced given the molecule shown and the electron flow indicated.

(a)

Identify the resonance structure that will be produced given the molecule shown and the electron flow indicated.

(c)