Problem 47b
(a) Which region of the periodic table shown here contains elements that are easiest to oxidize? (b) Which region contains the least readily oxidized elements?
Problem 48a,b,c
Determine the oxidation number of sulfur in each of the following substances: (a) barium sulfate, BaSO4 (b) sulfurous acid, H2SO3 (c) strontium sulfide, SrS
Problem 48d
Determine the oxidation number of sulfur in each of the following substances: (d) hydrogen sulfide, H2S
Problem 48e
Determine the oxidation number of sulfur in each of the following substances: (e) Locate sulfur in the periodic table in Exercise 4.47; what region is it in?
Problem 48f
Determine the oxidation number of sulfur in each of the following substances: (f) Which region(s) of the periodic table contains elements that can adopt both positive and negative oxidation numbers?
Problem 49a,b
Determine the oxidation number for the indicated element in each of the following substances: (a) S in SO3 (b) Ti in TiCl4
Problem 49c
Determine the oxidation number for the indicated element in each of the following substances: (c) P in AgPF6
Problem 49d
Determine the oxidation number for the indicated element in each of the following substances: (d) N in HNO3
Problem 50e,f
Determine the oxidation number for the indicated element in each of the following substances: (e) Pt in PtCl4 (f) O in OF2.
Problem 50f
Determine the oxidation number for the indicated element in each of the following substances: (f) Cl in NaClO4.
Problem 51a
Which element is oxidized, and which is reduced in the following reactions? (a) N2(g) + 3 H2(g) → 2 NH3(g)
Problem 51b
Which element is oxidized, and which is reduced in the following reactions? (b) 3 Fe(NO3)2(aq) + 2 Al(s) → 3 Fe(s) + 2 Al(NO3)3(aq)
Problem 51c,d
Which element is oxidized, and which is reduced in the following reactions? (c) Cl2(aq) + 2 NaI(aq) → I2(aq) + 2 NaCl(aq) (d) PbS(s) + 4 H2O2(aq) → PbSO4(s) + 4 H2O(l)
Problem 52
Which of the following are redox reactions? For those that are, indicate which element is oxidized and which is reduced. For those that are not, indicate whether they are precipitation or neutralization reactions. (a) P4(s) + 10 HClO(aq) + 6 H2O(l) → 4 H3PO4(aq) + 10 HCl(aq) (b) Br2(l) + 2 K(s)→ 2 KBr(s) (c) CH3CH2OH(l) + 3 O2(g) → 3 H2O(l) + 2 CO2(g) (d) ZnCl2(aq) + 2 NaOH(aq) → Zn(OH)2(s) + 2 NaCl(aq)
Problem 53
Write balanced molecular and net ionic equations for the reactions of (a) manganese with dilute sulfuric acid (b) chromium with hydrobromic acid (c) tin with hydrochloric acid (d) aluminum with formic acid, HCOOH.
Problem 54a,b
Write balanced molecular and net ionic equations for the reactions of (a) hydrochloric acid with nickel (b) dilute sulfuric acid with iron
Problem 54c,d
Write balanced molecular and net ionic equations for the reactions of (c) hydrobromic acid with magnesium (d) acetic acid, CH3COOH, with zinc.
Problem 55a,b
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (a) Iron metal is added to a solution of copper(II) nitrate (b) zinc metal is added to a solution of magnesium sulfate
Problem 55c
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (c) hydrobromic acid is added to tin metal
Problem 55d
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (d) hydrogen gas is bubbled through an aqueous solution of nickel(II) chloride
Problem 55e
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (e) aluminum metal is added to a solution of cobalt(II) sulfate.
Problem 56a
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (a) Nickel metal is added to a solution of copper(II) nitrate
Problem 56b,c
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (b) a solution of zinc nitrate is added to a solution of magnesium sulfate (c) hydrochloric acid is added to gold metal
Problem 56d
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (d) chromium metal is immersed in an aqueous solution of cobalt(II) chloride
Problem 56e
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (e) hydrogen gas is bubbled through a solution of silver nitrate.
Problem 57a
The metal cadmium tends to form Cd2+ ions. The following observations are made: (i) When a strip of zinc metal is placed in CdCl2(aq), cadmium metal is deposited on the strip. (ii) When a strip of cadmium metal is placed in Ni(NO3)(aq), nickel metal is deposited on the strip. (a) Write net ionic equations to explain each of the preceding observations.
Problem 57b
The metal cadmium tends to form Cd2+ ions. The following observations are made: (i) When a strip of zinc metal is placed in CdCl2(aq), cadmium metal is deposited on the strip. (ii) When a strip of cadmium metal is placed in Ni(NO3)(aq), nickel metal is deposited on the strip. (b) Which elements more closely define the position of cadmium in the activity series?
Problem 58a
The following reactions (note that the arrows are pointing only one direction) can be used to prepare an activity series for the halogens:
Br2(aq) + 2 NaI(aq) → 2 NaBr(aq) + I2(aq)
Cl2(aq) + 2 NaBr(aq) → 2 NaCl(aq) + Br2(aq)
(a) Which elemental halogen would you predict is the most stable, upon mixing with other halides?
Problem 58b
The following reactions (note that the arrows are pointing only one direction) can be used to prepare an activity series for the halogens:
Br2(aq) + 2 NaI(aq) → 2 NaBr(aq) + I2(aq)
Cl2(aq) + 2 NaBr(aq) → 2 NaCl(aq) + Br2(aq)
(b) Predict whether a reaction will occur when elemental chlorine and potassium iodide are mixed.
Problem 59a
(a) Is the number of moles of ions present in a solution an intensive or an extensive property?
Ch.4 - Reactions in Aqueous Solution