Problem 90a
(a) Ibuprofen is a common over-the-counter analgesic with the formula C13H18O2. How many moles of C13H18O2 are in a 500-mg tablet of ibuprofen? Assume the tablet is composed entirely of ibuprofen.
- CdSe quantum dots that are 6.5 nm in diameter emit red light upon stimulation. Assuming that the dot is a perfect sphere, calculate how many Cd atoms are in one quantum dot of this size.
Problem 91
Problem 91a
Very small semiconductor crystals, composed of approximately 1000 to 10,000 atoms, are called quantum dots. Quantum dots made of the semiconductor CdSe are now being used in electronic reader and tablet displays because they emit light efficiently and in multiple colors, depending on dot size. The density of CdSe is 5.82 g/cm3. (a) What is the mass of one 2.5-nm CdSe quantum dot?
Problem 91c
Very small semiconductor crystals, composed of approximately 1000 to 10,000 atoms, are called quantum dots. Quantum dots made of the semiconductor CdSe are now being used in electronic reader and tablet displays because they emit light efficiently and in multiple colors, depending on dot size. The density of CdSe is 5.82 g/cm3. (c) What is the mass of one 6.5-nm CdSe quantum dot?
Problem 91e
Very small semiconductor crystals, composed of approximately 1000 to 10,000 atoms, are called quantum dots. Quantum dots made of the semiconductor CdSe are now being used in electronic reader and tablet displays because they emit light efficiently and in multiple colors, depending on dot size. The density of CdSe is 5.82 g/cm3. (e) If you wanted to make one 6.5-nm dot from multiple 2.5-nm dots, how many 2.5-nm dots would you need, and how many CdSe formula units would be left over, if any?
Problem 92a
(a) One molecule of the antibiotic penicillin G has a mass of 5.342×10-21 g. What is the molar mass of penicillin G?
Problem 92b
(b) Hemoglobin, the oxygen-carrying protein in red blood cells, has four iron atoms per molecule and contains 0.340% iron by mass. Calculate the molar mass of hemoglobin.
- Cinnamaldehyde is a compound that is responsible for the characteristic aroma of cinnamon. It contains 81.79% C, 6.10% H, and the remaining is oxygen. Its molar mass is 132 g/mol. Determine its molecular formula.
Problem 93
- The fluoride ion reacts with water to produce HF. (a) Write out the chemical equation for this reaction.
Problem 94
Problem 95
Vanillin, the dominant flavoring in vanilla, contains C, H, and O. When 1.05 g of this substance is completely combusted, 2.43 g of CO2 and 0.50 g of H2O are produced. What is the empirical formula of vanillin?
Problem 96
An organic compound was found to contain only C, H, and Cl. When a 1.50-g sample of the compound was completely combusted in air, 3.52 g of CO2 was formed. In a separate experiment, the chlorine in a 1.00-g sample of the compound was converted to 1.27 g of AgCl. Determine the empirical formula of the compound.
- A compound, Na2Cr2Ox, where x is unknown, is analyzed and found to contain 39.70% Cr. What is the value of x?
Problem 97
Problem 98a,b
An element X forms an iodide (XI3) and a chloride (XCl3). The iodide is quantitatively converted to the chloride when it is heated in a stream of chlorine: 2 XI3 + 3 Cl2 → 2 XCl3 + 3 I2 If 0.5000 g of XI3 is treated with chlorine, 0.2360 g of XCl3 is obtained. (a) Calculate the atomic weight of the element X. (b) Identify the element X.
Problem 99a
A method used by the U.S. Environmental Protection Agency (EPA) for determining the concentration of ozone in air is to pass the air sample through a 'bubbler' containing sodium iodide, which removes the ozone according to the following equation: O31g2 + 2 NaI1aq2 + H2O1l2¡ O21g2 + I21s2 + 2 NaOH1aq2 (a) How many moles of sodium iodide are needed to remove 5.95 * 10-6 mol of O3?
Problem 99b
A method used by the U.S. Environmental Protection Agency (EPA) for determining the concentration of ozone in air is to pass the air sample through a 'bubbler' containing sodium iodide, which removes the ozone according to the following equation: O31g2 + 2 NaI1aq2 + H2O1l2¡ O21g2 + I21s2 + 2 NaOH1aq2 (b) How many grams of sodium iodide are needed to remove 1.3 mg of O3?
Problem 101
The fat stored in a camel's hump is a source of both energy and water. Calculate the mass of H2O produced by the metabolism of 1.0 kg of fat, assuming the fat consists entirely of tristearin 1C57H110O62, a typical animal fat, and assuming that during metabolism, tristearin reacts with O2 to form only CO2 and H2O.
- When hydrocarbons are burned in a limited amount of air, both CO and CO2 form. When 0.450 g of a particular hydrocarbon was burned in air, 0.467 g of CO, 0.733 g of CO2, and 0.450 g of H2O were formed. (a) What is the empirical formula of the compound? (b) How many grams of O2 were used in the reaction? (c) How many grams would have been required for complete combustion?
Problem 102
Problem 103
A mixture of N21g2 and H21g2 reacts in a closed container to form ammonia, NH31g2. The reaction ceases before either reactant has been totally consumed. At this stage 3.0 mol N2, 3.0 mol H2, and 3.0 mol NH3 are present. How many moles of N2 and H2 were present originally?
Problem 104
A mixture containing KClO3, K2CO3, KHCO3, and KCl was heated, producing CO2, O2, and H2O gases according to the following equations: 2 KClO31s2¡2 KCl1s2 + 3 O21g2 2 KHCO31s2¡K2O1s2 + H2O1g2 + 2 CO21g2 K2CO31s2¡K2O1s2 + CO21g2 The KCl does not react under the conditions of the reaction. If 100.0 g of the mixture produces 1.80 g of H2O, 13.20 g of CO2, and 4.00 g of O2, what was the composition of the original mixture? (Assume complete decomposition of the mixture.) How many grams of K2CO3 were in the original mixture?
Problem 105c3
When a mixture of 10.0 g of acetylene (C2H2) and 10.0 g of oxygen (O2) is ignited, the resulting combustion reaction produces CO2 and H2O. (c) How many grams of CO2 and H2O are present after the reaction is complete?
Problem 105c1
When a mixture of 10.0 g of acetylene (C2H2) and 10.0 g of oxygen (O2) is ignited, the resulting combustion reaction produces CO2 and H2O. (c) How many grams of C2H2 are present after the reaction is complete?
- Boron nitride, BN, is an electrical insulator with remarkable thermal and chemical stability. Its density is 2.1 g/cm3. It can be made by reacting boric acid, H3BO3, with ammonia. The other product of the reaction is water. (b) If you made 225 g of boric acid react with 150 g of ammonia, what mass of BN could you make? (d) One application of BN is as a thin film for electrical insulation. If you take the mass of BN from part (b) and make a 0.4 mm thin film from it, what area, in cm2, would it cover?
Problem 106
- Viridicatumtoxin B, C30H31NO10, is a natural antibiotic compound. It requires a synthesis of 12 steps in the laboratory. Assuming all steps have equivalent yields of 85%, which is the final percent yield of the total synthesis?
Problem 107
Problem 109b
(b) Because atoms are spherical, they cannot occupy all of the space of the cube. The silver atoms pack in the solid in such a way that 74% of the volume of the solid is actually filled with the silver atoms. Calculate the volume of a single silver atom.
Problem 109c
Burning acetylene in oxygen can produce three different carbon-containing products: soot (very fine particles of graphite), CO(g), and CO2(g). (c) Why, when the oxygen supply is adequate, is CO2(g) the predominant carbon-containing product of the combustion of acetylene?
- Section 2.9 introduced the idea of structural isomerism, with 1-propanol and 2-propanol as examples. Determine which of these properties would distinguish these two substances: (a) boiling point, (b) combustion analysis results, (c) molecular weight, (d) density at a given temperature and pressure. You can check on the properties of these two compounds in Wolfram Alpha (http://www.wolframalpha.com/) or the CRC Handbook of Chemistry and Physics.
Problem 111
- A 3.50 g of an alloy which contains only lead and tin is dissolved in hot HNO3. Excess sulfuric acid is added to this solution and 1.57g of PbSO4(s) is obtained. (b) Assuming all the lead in the alloy reacted to form PbSO4, what was the amount, in grams, of lead and tin in the alloy respectively?
Problem 112
Problem 113a,b
Hydrogen cyanide, HCN, is a poisonous gas. The lethal dose is approximately 300 mg HCN per kilogram of air when inhaled. (a) Calculate the amount of HCN that gives the lethal dose in a small laboratory room measuring 3.5 × 4.5 × 2.5 m. The density of air at 26 °C is 0.00118 g/cm3. (b) If the HCN is formed by reaction of NaCN with an acid such as H2SO4, what mass of NaCN gives the lethal dose in the room? 2 NaCN(s) + H2SO4(aq) → Na2SO4(aq) + 2 HCN(g)
Problem 113c
Hydrogen cyanide, HCN, is a poisonous gas. The lethal dose is approximately 300 mg HCN per kilogram of air when inhaled. (c) HCN forms when synthetic fibers containing Orlon® or Acrilan ® burn. Acrilan® has an empirical formula of CH2CHCN, so HCN is 50.9% of the formula by mass. A rug measures 3.5 × 4.5 m and contains 850 g of Acrilan® fibers per square yard of carpet. If the rug burns, will a lethal dose of HCN be generated in the room? Assume that the yield of HCN from the fibers is 20% and that the carpet is 50% consumed.
Problem 114a
The source of oxygen that drives the internal combustion engine in an automobile is air. Air is a mixture of gases, principally N2(79%) and O2(20%). In the cylinder of an automobile engine, nitrogen can react with oxygen to produce nitric oxide gas, NO. As NO is emitted from the tailpipe of the car, it can react with more oxygen to produce nitrogen dioxide gas. (a) Write balanced chemical equations for both reactions.
Ch.3 - Chemical Reactions and Reaction Stoichiometry