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Problem 99b
It is common in mass spectrometry to assume that the mass of a cation is the same as that of its parent atom. (b) What percentage of the mass of an 1H atom does the electron represent?
Problem 100
From the following list of elements—Mg, Li, Tl, Pb, Se, Cl, Xe, Si, C—pick the one that best fits each description. Use each element only once: (a) an alkali metal, (b) an alkaline earth metal, (c) a noble gas, (d) a halogen, (e) a metalloidin group 14, (f) a nonmetal listed in group 14, (g) a metal that forms a 3+ ion, (h) a nonmetal that forms a 2- ion, (i) an element that is used as radiation shielding.
Problem 101a
The first atoms of seaborgium (Sg) were identified in 1974. The longest-lived isotope of Sg has a mass number of 266. (a) How many protons, electrons, and neutrons are in an 266Sg atom?
Problem 101b
The first atoms of seaborgium (Sg) were identified in 1974. The longest-lived isotope of Sg has a mass number of 266. (b) Atoms of Sg are very unstable, and it is therefore difficult to study this element's properties. Based on the position of Sg in the periodic table, what element should it most closely resemble in its chemical properties?
- The explosion of an atomic bomb releases many radioactive isotopes, including strontium-90. Considering the location of strontium in the periodic table, suggest a reason why this isotope is particularly dangerous for human health.
Problem 102
- Calculate the value of the silver in the American Silver Eagle coin, assuming its thickness is uniform, given that it has a diameter of 41 mm, a thickness of 2.5 mm, a silver density of 10.5 g/cm3, and the approximate market price of silver is $0.51 per gram.
Problem 104
Problem 105
From the molecular structures shown here, identify the one that corresponds to each of the following species: (a) chlorine gas; (b) propane; (c) nitrate ion; (d) sulfur trioxide; (e) methyl chloride, CH3Cl.
- Name each of the following chlorides. Assuming that the compounds are ionic, what charge is associated with the metallic element in each case? (a) AgCl (b) TiCl₄ (c) IrCl₃ (d) LiCl.
Problem 106
Problem 107a
Fill in the blanks in the following table:
Cation Anion Formula Name
Lithium oxide
Fe2+ PO43-
Al2(SO4)3
Copper(II) nitrate
Cr3+ I−
MnClO2
Ammonium carbonate
Zinc perchlorate
Complete the first column of the table.
Problem 107c,d
Fill in the blanks in the following table:
Cation Anion Formula Name
Lithium oxide
Fe2+ PO43-
Al2(SO4)3
Copper(II) nitrate
Cr3+ I−
MnClO2
Ammonium carbonate
Zinc perchlorate
Complete the third column of the table.
Complete the fourth column of the table.
- Consider a sample of calcium carbonate in the form of a cube measuring 2.005 in. on each edge. If the sample has a density of 2.71 g>cm3, how many oxygen atoms does it contain?
Problem 108
Problem 108a2
Cyclopropane is an interesting hydrocarbon. Instead of having three carbons in a row, the three carbons form a ring, as shown in this perspective drawing (see Figure 2.18 for a prior example of this kind of drawing):
Cyclopropane was at one time used as an anesthetic, but its use was discontinued, in part because it is highly flammable. (a) How does it differ from that of propane?
Problem 108b
Cyclopropane is an interesting hydrocarbon. Instead of having three carbons in a row, the three carbons form a ring, as shown in this perspective drawing (see Figure 2.18 for a prior example of this kind of drawing):
Cyclopropane was at one time used as an anesthetic, but its use was discontinued, in part because it is highly flammable. (b) The three carbon atoms are necessarily in a plane. What do the different wedges mean?
Problem 109a,b,c
Elements in the same group of the periodic table often form oxyanions with the same general formula. The anions are also named in a similar fashion. Based on these observations, suggest a chemical formula or name, as appropriate, for each of the following ions: (a) BrO4- (b) SeO32- (c) arsenate ion
Problem 109d
Elements in the same group of the periodic table often form oxyanions with the same general formula. The anions are also named in a similar fashion. Based on these observations, suggest a chemical formula or name, as appropriate, for each of the following ions: (d) hydrogen tellurate ion.
Problem 110
Carbonic acid occurs in carbonated beverages. When allowed to react with lithium hydroxide, it produces lithium carbonate. Lithium carbonate is used to treat depression and bipolar disorder. Write chemical formula for carbonic acid, lithium hydroxide, and lithium carbonate.
- Give the chemical names of each of the following familiar compounds: (a) NaCl (table salt) (b) NaHCO3 (baking soda) (c) NaOCl (in many bleaches) (d) NaOH (caustic soda) (e) (NH4)2CO3 (smelling salts) (f) CaSO4 (plaster of Paris).
Problem 111
Problem 112
Many familiar substances have common, unsystematic names. For each of the following, give the correct systematic name: (a) salt peter, KNO3 (b) soda ash, Na2CO3 (c) lime, (d) muriatic acid, HCl, CaO (e) Epsom salts, MgSO4 (f) milk of magnesia, Mg(OH)2.
Problem 113a,b,c,d
Because many ions and compounds have very similar names, there is great potential for confusing them. Write the correct chemical formulas to distinguish between (a) sodium carbonate and sodium bicarbonate, (b) potassium peroxide and potassium oxide, (c) aluminum nitride and aluminum nitrite, (d) iron(II) oxide and iron(III) oxide
Problem 113e,f,g,h
Because many ions and compounds have very similar names, there is great potential for confusing them. Write the correct chemical formulas to distinguish between (e) hydride ion and hydroxide ion, (f) magnesium nitride and magnesium nitrite, (g) mercurous chloride and mercuric chloride, (h) cuprous oxide and cupric oxide.
- In what part of the atom does the strong nuclear force operate?
Problem 114