BackA dibromide loses only one bromine when it reacts with sodium hydroxide. The dibromide forms toluene (C6H5-CH3) when it reacts with magnesium shavings in ether followed by treatment with dilute acid. Give possible structures for the dibromide.
What is the major product of each of the following reactions?
c.
d.
Using the given starting material, any necessary inorganic reagents and catalysts, and any carbon-containing compounds with no more than three carbons, indicate how each of the following compounds can be prepared:
e.
The Reformatsky reaction is an addition reaction in which an organozinc reagent is used instead of a Grignard reagent to add to the carbonyl group of an aldehyde or a ketone. Because the organozinc reagent is less reactive than a Grignard reagent, a nucleophilic addition to the ester group does not occur.
The organozinc reagent is prepared by treating an α-bromo ester with zinc.
Describe how each of the following compounds can be prepared, using a Reformatsky reaction:
d.
Identify A through H
Fill in the boxes with the appropriate reagents:
Using the given starting material, any necessary inorganic reagents and catalysts, and any carbon-containing compounds with no more than two carbons, indicate how each of the following compounds can be prepared:
a.
Using the given starting material, any necessary inorganic reagents and catalysts, and any carbon-containing compounds with no more than two carbons, indicate how each of the following compounds can be prepared:
c.
Using the given starting material, any necessary inorganic reagents, and any carbon-containing compounds with no more than two carbons, indicate how each of the following compounds can be prepared:
b.
Using bromocyclohexane as a starting material, how could you synthesize the following compounds?
d.
How can the following compounds be prepared from the given starting materials?
c.
Show how each of the following compounds can be prepared, using the given starting material:
e.
Identify A through O:
a. Show the reagents required to form the primary alcohol in each of the following reactions.
a. Show the reagents required to form the primary alcohol in each of the following reactions.