Textbook Question
Using condensed structural formulas, or line-angle formulas if cyclic, write the balanced chemical equations for the (1) reaction of each of the following amines with water and (2) neutralization with HBr:
c. N-methylaniline
Ch.14 Carboxylic Acids, Esters, Amines, and Amides
Timberlake14thChemistry: An Introduction to General, Organic, and Biological ChemistryISBN: 9781292472249
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Table of contents
- Ch.1 Chemistry in Our Lives19
- Ch.2 Chemistry and Measurements80
- Ch.3 Matter and Energy53
- Ch.4 Atoms and Elements58
- Ch.5 Nuclear Chemistry42
- Ch.6 Ionic and Molecular Compounds57
- Ch.7 Chemical Quantities and Reactions38
- Ch.8 Gases30
- Ch.9 Solutions50
- Ch.10 Acids and Bases and Equilibrium64
- Ch.11 Introduction to Organic Chemistry: Hydrocarbons77
- Ch.12 Alcohols, Thiols, Ethers, Aldehydes, and Ketones82
- Ch.13 Carbohydrates54
- Ch.14 Carboxylic Acids, Esters, Amines, and Amides91
- Ch.15 Lipids61
- Ch.16 Amino Acids, Proteins, and Enzymes84
- Ch.17 Nucleic Acids and Protein Synthesis86
- Ch.18 Metabolic Pathways and ATP Production73
Timberlake14thChemistry: An Introduction to General, Organic, and Biological ChemistryISBN: 9781292472249Not the one you use?Change textbook
Chapter 14, Problem 40c
Draw the condensed structural or line-angle formula for the amide formed in each of the following reactions:
c. 
Verified step by step guidance1
Identify the reactants in the given reaction. In the formation of an amide, the reactants typically include a carboxylic acid (or its derivative) and an amine (primary or secondary). Analyze the structure of the reactants provided in the image.
Understand the reaction mechanism. The carboxylic acid (or its derivative) reacts with the amine, where the hydroxyl group (-OH) of the carboxylic acid is replaced by the amine group (-NH2 or -NHR) to form the amide bond (-CONH-).
Determine the structure of the amide product. Combine the carbonyl group (C=O) from the carboxylic acid with the nitrogen atom from the amine, ensuring the correct connectivity of atoms.
Draw the condensed structural formula for the amide. Write the formula by grouping atoms together to represent the structure compactly, such as CH3CONH2 for acetamide.
Alternatively, draw the line-angle formula for the amide. Use lines to represent bonds between carbon atoms, with the carbonyl group and amine group clearly depicted. Ensure the drawing reflects the correct geometry and connectivity of the molecule.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Amides
Amides are organic compounds derived from carboxylic acids where the hydroxyl group (-OH) is replaced by an amine group (-NH2, -NHR, or -NR2). They are characterized by the functional group -C(=O)N-, which is crucial for understanding their structure and reactivity. Amides can be formed through the reaction of carboxylic acids with amines, and they play significant roles in biochemistry, particularly in the formation of proteins.
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Intro to Amides Example 1
Condensed Structural Formula
A condensed structural formula is a way of representing a chemical structure that shows the arrangement of atoms in a molecule without depicting all the bonds explicitly. In this format, groups of atoms are grouped together, and the connectivity is implied rather than drawn out. This method is useful for simplifying complex structures and is commonly used in organic chemistry to convey information quickly and efficiently.
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Line-Angle Formula
The line-angle formula, also known as the skeletal formula, is a shorthand representation of organic molecules where vertices represent carbon atoms and lines represent bonds. This method omits hydrogen atoms attached to carbons, making it easier to visualize larger organic structures. Understanding line-angle formulas is essential for interpreting chemical structures quickly, especially in the context of organic reactions and mechanisms.
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Related Practice
Textbook Question
Draw the condensed structural or line-angle formula for the amide formed in each of the following reactions:
a.
Textbook Question
Draw the condensed structural or line-angle formula for the amide formed in each of the following reactions:
c.
Textbook Question
Write the IUPAC and common names, if any, for each of the following amides:
c.
Textbook Question
Draw the condensed structural formula for a and b and the line-angle formula for c and d:
b. 2-methylpentanamide
Textbook Question
Draw the condensed structural formula for a and b and the line-angle formula for c and d:
a. heptanamide