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Problem 62c
Two 25.0-mL samples, one 0.100 M HCl and the other 0.100 M HF, are titrated with 0.200 M KOH. c. Which titration curve has the lower initial pH?
Problem 62d
Two 25.0-mL samples, one 0.100 M HCl and the other 0.100 M HF, are titrated with 0.200 M KOH.
d. Sketch each titration curve.
Problem 63a
Two 20.0-mL samples, one 0.200 M KOH and the other 0.200 M CH3NH2, are titrated with 0.100 M HI. a. What is the volume of added acid at the equivalence point for each titration?
Problem 63b
Two 20.0-mL samples, one 0.200 M KOH and the other 0.200 M CH3NH2, are titrated with 0.100 M HI. b. Is the pH at the equivalence point for each titration acidic, basic, or neutral?
Problem 63c
Two 20.0-mL samples, one 0.200 M KOH and the other 0.200 M CH3NH2, are titrated with 0.100 M HI. c. Which titration curve has the lower initial pH?
Problem 63d
Two 20.0-mL samples, one 0.200 M KOH and the other 0.200 M CH3NH2, are titrated with 0.100 M HI. d. Sketch each titration curve.
Problem 64b
The graphs labeled (a) and (b) show the titration curves for two equal-volume samples of bases, one weak and one strong. Both titrations were carried out with the same concentration of strong acid.
(ii) Which graph corresponds to the titration of the strong base and which one to the weak base?
Problem 65c
Consider the curve shown here for the titration of a weak monoprotic acid with a strong base and answer each question.
c. At what volume of added base does pH = pKa?
Problem 65d
Consider the curve shown here for the titration of a weak monoprotic acid with a strong base and answer each question.
d. At what volume of added base is the pH calculated by working an equilibrium problem based on the concentration and Kb of the conjugate base?
Problem 66a
Consider the curve shown here for the titration of a weak base with a strong acid and answer each question.
a. What is the pH and what is the volume of added acid at the equivalence point?
Problem 66c
Consider the curve shown here for the titration of a weak base with a strong acid and answer each question.
c. At what volume of added acid does pH = 14 - pKb?
Problem 66d
Consider the curve shown here for the titration of a weak base with a strong acid and answer each question.
d. At what volume of added acid is the pH calculated by working an equilibrium problem based on the concentration and Ka of the conjugate acid?
Problem 67a
Consider the titration of a 35.0-mL sample of 0.175 M HBr with 0.200 M KOH. Determine each quantity. a. the initial pH
Problem 67b
Consider the titration of a 35.0-mL sample of 0.175 M HBr with 0.200 M KOH. Determine each quantity. b. the volume of added base required to reach the equivalence point
Problem 67c
Consider the titration of a 35.0-mL sample of 0.175 M HBr with 0.200 M KOH. Determine each quantity. c. the pH at 10.0 mL of added base
Problem 67d
Consider the titration of a 35.0-mL sample of 0.175 M HBr with 0.200 M KOH. Determine each quantity. d. the pH at the equivalence point
Problem 67e
Consider the titration of a 35.0-mL sample of 0.175 M HBr with 0.200 M KOH. Determine each quantity. e. the pH after adding 5.0 mL of base beyond the equivalence point
Problem 68
A 20.0-mL sample of 0.125 M HNO3 is titrated with 0.150 M NaOH. Calculate the pH for at least five different points throughout the titration curve and sketch the curve. Indicate the volume at the equivalence point on your graph.
- Consider the titration of a 25.0-mL sample of 0.115 M RbOH with 0.100 M HCl. Determine each quantity. a. the initial pH d. the pH at the equivalence point e. the pH after adding 5.0 mL of acid beyond the equivalence point
Problem 69
Problem 69b
Consider the titration of a 25.0-mL sample of 0.115 M RbOH with 0.100 M HCl. Determine each quantity. b. the volume of added acid required to reach the equivalence point
Problem 69c
Consider the titration of a 25.0-mL sample of 0.115 M RbOH with 0.100 M HCl. Determine each quantity. c. the pH at 5.0 mL of added acid
Problem 71b
Consider the titration of a 20.0-mL sample of 0.105 M HC2H3O2 with 0.125 M NaOH. Determine each quantity. b. the volume of added base required to reach the equivalence point
Problem 72
A 30.0-mL sample of 0.165 M propanoic acid is titrated with 0.300 M KOH. Calculate the pH at each volume of added base: 0 mL, 5 mL, 10 mL, equivalence point, one-half equivalence point, 20 mL, 25 mL. Sketch the titration curve.
Problem 72a
A 30.0-mL sample of 0.165 M propanoic acid is titrated with 0.300 M KOH. Calculate the pH at each volume of added base: 0 mL.
Problem 72b
A 30.0-mL sample of 0.165 M propanoic acid is titrated with 0.300 M KOH. Calculate the pH at each volume of added base: 5 mL.
Problem 72c
A 30.0-mL sample of 0.165 M propanoic acid is titrated with 0.300 M KOH. Calculate the pH at each volume of added base: 10 mL.
Problem 72d
A 30.0-mL sample of 0.165 M propanoic acid is titrated with 0.300 M KOH. Calculate the pH at each volume of added base: equivalence point.
Problem 72e
A 30.0-mL sample of 0.165 M propanoic acid is titrated with 0.300 M KOH. Calculate the pH at each volume of added base: one-half equivalence point.
Problem 72f
A 30.0-mL sample of 0.165 M propanoic acid is titrated with 0.300 M KOH. Calculate the pH at each volume of added base: 20 mL.
Problem 72g
A 30.0-mL sample of 0.165 M propanoic acid is titrated with 0.300 M KOH. Calculate the pH at each volume of added base: 25 mL.