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Ch.19 - Electrochemistry
Chapter 19, Problem 75

List the following reducing agents in order of increasing strength under standard-state conditions: Al(s), Pb(s), Fe(s).

Verified step by step guidance
1
Step 1: Understand that a reducing agent is a substance that donates electrons in a redox reaction, causing another substance to be reduced.
Step 2: Recognize that the strength of a reducing agent is related to its ability to lose electrons, which can be determined by its standard reduction potential (E°).
Step 3: Look up the standard reduction potentials for the given metals: Al(s), Pb(s), and Fe(s). These values are typically found in a table of standard reduction potentials.
Step 4: Note that the more negative the standard reduction potential, the stronger the reducing agent, because it indicates a greater tendency to lose electrons.
Step 5: Arrange the metals in order of increasing strength as reducing agents by comparing their standard reduction potentials, from the least negative to the most negative value.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Reducing Agents

Reducing agents are substances that donate electrons in a chemical reaction, thereby reducing another species. They undergo oxidation themselves, losing electrons and increasing their oxidation state. The strength of a reducing agent is determined by its ability to lose electrons easily, which is often related to its position in the electrochemical series.
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Standard-State Conditions

Standard-state conditions refer to a set of specific conditions used to measure and compare the properties of substances, typically defined as 1 bar of pressure and a specified temperature, usually 25°C. Under these conditions, the behavior of reducing agents can be consistently evaluated, allowing for a reliable comparison of their strengths.
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Electrochemical Series

The electrochemical series is a list of standard electrode potentials for various half-reactions, arranged from the strongest reducing agents to the strongest oxidizing agents. By comparing the standard reduction potentials of the metals in question (Al, Pb, Fe), one can determine their relative strengths as reducing agents, with more negative potentials indicating stronger reducing capabilities.
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