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Multiple Choice
What volume, in liters, of carbon monoxide gas at 78.5 °C and 848 torr is needed to produce 4.54 g of methanol, CH₃OH, according to the reaction: CO(g) + 2 H₂(g) → CH₃OH(g)?
A
5.00 L
B
2.50 L
C
3.75 L
D
1.25 L
Verified step by step guidance
1
First, convert the mass of methanol (CH₃OH) to moles using its molar mass. The molar mass of CH₃OH is approximately 32.04 g/mol. Use the formula: \( \text{moles of CH₃OH} = \frac{\text{mass of CH₃OH}}{\text{molar mass of CH₃OH}} \).
Next, use the stoichiometry of the balanced chemical equation \( \text{CO(g) + 2 H₂(g) → CH₃OH(g)} \) to determine the moles of CO needed. According to the equation, 1 mole of CH₃OH is produced from 1 mole of CO.
Convert the pressure from torr to atm, as the ideal gas law requires pressure in atm. Use the conversion: \( 1 \text{ atm} = 760 \text{ torr} \). Therefore, \( \text{pressure in atm} = \frac{848 \text{ torr}}{760 \text{ torr/atm}} \).
Convert the temperature from Celsius to Kelvin, as the ideal gas law requires temperature in Kelvin. Use the formula: \( \text{temperature in K} = \text{temperature in °C} + 273.15 \).
Finally, use the ideal gas law \( PV = nRT \) to solve for the volume \( V \) of CO gas. Rearrange the equation to \( V = \frac{nRT}{P} \), where \( n \) is the moles of CO, \( R \) is the ideal gas constant (0.0821 L·atm/mol·K), \( T \) is the temperature in Kelvin, and \( P \) is the pressure in atm.