Ch. 15 - Structural Identification II: Nuclear Magnetic Resonance Spectroscopy
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Mullins 1st Edition
Ch. 15 - Structural Identification II: Nuclear Magnetic Resonance Spectroscopy


Problem 80
The spectral data below are presented in a manner similar to what you would find in a chemistry research journal. Identify the structure for each set of data.
(c) C₇H₁₄O₂ : ¹H NMR: δ 0.91 (3H, t, J = 7.0 Hz), 1.11 (6H, d, J = 7.0 Hz), 1.82 (2H, sextet), 2.40 (1H, sept, J = 7.0 Hz), 4.14 (2H, t, J = 7.1 Hz); IR (cm ⁻¹) : 1745, 1200
Problem 81a
(a) Using the ¹H NMR spectra, identify the reactants and product for this reaction.
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Problem 81b
(b) Provide an arrow-pushing mechanism for the reaction.
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