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Organic Chemistry 1 Midterm - Part 2 of 3
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Problem 1
Problem 2
Problem 3
Problem 4
Problem 5
Problem 6
Problem 7
Problem 8
Problem 9
Problem 10
Problem 11
Problem 12
Problem 13
Problem 14
Problem 15
Problem 16
Problem 17
Problem 18
Problem 19
Problem 20
Problem 21
Problem 22
Problem 23
Problem 24
Problem 25
Organic Chemistry 1 Midterm - Part 2 of 3
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4. Alkanes and Cycloalkanes / Equatorial Preference / Problem 18
Problem 18
Determine whether the
cis
isomer or the
trans
isomer of the following compound is more stable.
A
The less bulky group
(iso-propyl)
is at the equatorial position and
(tert-butyl)
is at the axial position. Thus, the
trans
-conformation is more stable.
B
The bulkier group
(tert-butyl)
is at the equatorial position and
(iso-propyl)
is also at the equatorial position. Thus, the
cis
-conformation is more stable.
C
The bulkier group
(tert-butyl)
is at the equatorial position and
(iso-propyl)
is at the axial position. Thus, the
cis
-conformation is more stable.
D
The bulkier group
(tert-butyl)
is at the axial position and
(iso-propyl)
is also at the axial position. Thus, the
cis
-conformation is more stable.
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