Problem 53
According to Coulomb's law, which pair of charged particles has the lowest potential energy? a. a particle with a 1- charge separated by 150 pm from a particle with a 2+ charge b. a particle with a 1- charge separated by 150 pm from a particle with a 1+ charge c. a particle with a 1- charge separated by 100 pm from a particle with a 3+ charge
Problem 54
According to Coulomb's law, rank the interactions between charged particles from lowest potential energy to highest potential energy. a. a 1+ charge and a 1- charge separated by 100 pm b. a 2+ charge and a 1- charge separated by 100 pm c. a 1+ charge and a 1+ charge separated by 100 pm d. a 1+ charge and a 1- charge separated by 200 pm
Problem 55
Which experience a greater effective nuclear charge: the valence electrons in beryllium or the valence electrons in nitrogen? Why?
Problem 56
Arrange the atoms according to decreasing effective nuclear charge experienced by their valence electrons: S, Mg, Al, Si.
Problem 57a
If core electrons completely shielded valence electrons from nuclear charge (i.e., if each core electron reduced nuclear charge by 1 unit) and if valence electrons did not shield one another from nuclear charge at all, what would be the effective nuclear charge experienced by the valence electrons of each atom? a. K
Problem 57b
If core electrons completely shielded valence electrons from nuclear charge (i.e., if each core electron reduced nuclear charge by 1 unit) and if valence electrons did not shield one another from nuclear charge at all, what would be the effective nuclear charge experienced by the valence electrons of each atom? b. Ca
Problem 57c,d
If core electrons completely shielded valence electrons from nuclear charge (i.e., if each core electron reduced nuclear charge by 1 unit) and if valence electrons did not shield one another from nuclear charge at all, what would be the effective nuclear charge experienced by the valence electrons of each atom? c. O d. C
Problem 58
In Section 3.6, we estimated the effective nuclear charge on beryllium's valence electrons to be slightly greater than 2+. What would a similar treatment predict for the effective nuclear charge on boron's valence electrons? Would you expect the effective nuclear charge to be different for boron's 2s electrons compared to its 2p electron? In what way? (Hint: Consider the shape of the 2p orbital compared to that of the 2s orbital.)
Problem 59
Choose the larger atom in each pair. a. Al or In b. Si or N c. P or Pb d. Si or Cl
Problem 60
Choose the larger atom in each pair. a. Sn or Si b. Br or Ga c. Sn or Bi d. Se or Sn
- Arrange these elements in order of increasing atomic radius: F, S, Si, Ge, Ca, Rb.
Problem 61
- Arrange these elements in order of decreasing atomic radius: Cs, Pb, Sb, Se, S.
Problem 62
Problem 63a
Write the electron configuration for each ion. a. O2-
Problem 63b
Write the electron configuration for each ion. b. Br-
Problem 64a
Write the electron configuration for each ion. a. Cl-
Problem 64b
Write the electron configuration for each ion. b. P3-
Problem 64c
Write the electron configuration for each ion. c. K+
Problem 64d,e
Write the electron configuration for each ion. d. Mo3+ e. V3+
Problem 65
Write orbital diagrams for each of these ions.Determine if the ion is diamagnetic or paramagnetic. a. V5+ b. Cr3+ c. Ni2+ d. Fe3+
Problem 66
Write orbital diagrams for each ion and determine if the ion is diamagnetic or paramagnetic. a. Cd2+ b. Au+ c. Mo3+ d. Zr2+
Problem 67
Which is the larger species in each pair? a. Li or Li+ b. Cs- or Cs+ c. Cr- or Cr3+ d. O or O2-
Problem 68
Which is the larger species in each pair? a. Sr or Sr2+ b. N or N3- c. Ni or Ni2+ d. S2- or Ca2+
- Arrange this isoelectronic series in order of decreasing radius: O2-, F-, Na+, Mg2+.
Problem 69
Problem 70
Arrange this isoelectronic series in order of increasing atomic radius: Se2- , Sr2+ , Rb+ , Br- .
Problem 71a
Choose the element with the higher first ionization energy from each pair. a. Br or Bi
Problem 71b
Choose the element with the higher first ionization energy from each pair. b. Na or Rb
Problem 71c
Choose the element with the higher first ionization energy from each pair. c. As or At
Problem 71d
Choose the element with the higher first ionization energy from each pair. d. P or Sn
Problem 72
Choose the element with the higher first ionization energy from each pair. a. P or I b. Si or Cl c. P or Sb d. Ga or Ge
Problem 73
Arrange these elements in order of increasing first ionization energy: Si, F, In, N.
Ch.9 - Periodic Properties of the Elements