Determine whether each process is exothermic or endothermic and indicate the sign of ΔH. a. dry ice evaporating b. a sparkler burning c. the reaction that occurs in a chemical cold pack used to ice athletic injuries

What mass of natural gas (CH₄) must burn to emit 267 kJ of heat? CH₄(g) + 2 O₂(g) → CO₂(g) + 2 H₂O(g) ΔH°_rxn = –802.3 kJ

Nitromethane (CH₃NO₂) burns in air to produce significant amounts of heat. 2 CH₃NO₂(l) + 3/2 O₂(g) → 2 CO₂(g) + 3 H₂O(l) + N₂(g) ΔH°_rxn = –1418 kJ How much heat is produced by the complete reaction of 5.56 kg of nitromethane?

Titanium reacts with iodine to form titanium(III) iodide, emitting heat. 2 Ti(s) + 3 I₂(g) → 2 TiI₃(s) ΔH°_rxn = –839 kJ Determine the mass of titanium that react if 1.55×10³ kJ of heat is emitted by the reaction.

The propane fuel (C₃H₈) used in gas barbeques burns according to the thermochemical equation: C₃H₈(g) + 5 O₂(g) → 3 CO₂(g) + 4 H₂O(g) ΔH°_rxn = –2044 kJ If a pork roast must absorb 1.6×10³ kJ to fully cook, and if only 10% of the heat produced by the barbeque is actually absorbed by the roast, what mass of CO₂ is emitted into the atmosphere during the grilling of the pork roast?

Charcoal is primarily carbon. Determine the mass of CO₂ produced by burning enough carbon (in the form of charcoal) to produce 5.00×10² kJ of heat. C(s) + O₂(g) → CO₂(g) ΔH°_rxn = –393.5 kJ

A silver block, initially at 58.5 °C, is submerged into 100.0 g of water at 24.8 °C, in an insulated container. The final temperature of the mixture upon reaching thermal equilibrium is 26.2 °C. What is the mass of the silver block?

A 32.5-g iron rod, initially at 22.7 °C, is submerged into an unknown mass of water at 63.2 °C, in an insulated container. The final temperature of the mixture upon reaching thermal equilibrium is 59.5 °C. What is the mass of the water?

A 31.1-g wafer of pure gold, initially at 69.3 °C, is submerged into 64.2 g of water at 27.8 °C in an insulated container. What is the final temperature of both substances at thermal equilibrium?

A 2.85-g lead weight, initially at 10.3 °C, is submerged in 7.55 g of water at 52.3 °C in an insulated container. What is the final temperature of both substances at thermal equilibrium?

Two substances, A and B, initially at different temperatures, come into contact and reach thermal equilibrium. The mass of substance A is 6.15 g and its initial temperature is 20.5 °C. The mass of substance B is 25.2 g and its initial temperature is 52.7 °C. The final temperature of both substances at thermal equilibrium is 46.7 °C. If the specific heat capacity of substance B is 1.17 J/g•°C, what is the specific heat capacity of substance A?

Exactly 1.5 g of a fuel burns under conditions of constant pressure and then again under conditions of constant volume. In measurement A the reaction produces 25.9 kJ of heat, and in measurement B the reaction produces 23.3 kJ of heat. Which measurement (A or B) corresponds to conditions of constant pressure? Explain.

When 0.514 g of biphenyl (C₁₂H₁₀) undergoes combustion in a bomb calorimeter, the temperature rises from 25.8 °C to 29.4 °C. Find ΔE_rxn for the combustion of biphenyl in kJ/mol biphenyl. The heat capacity of the bomb calorimeter, determined in a separate experiment, is 5.86 kJ/°C.

Mothballs are composed primarily of the hydrocarbon naphthalene (C₁₀H₈). When 1.025 g of naphthalene burns in a bomb calorimeter, the temperature rises from 24.25 °C to 32.33 °C. Find ΔE_rxn for the combustion of naphthalene. The heat capacity of the bomb calorimeter, determined in a separate experiment, is 5.11 kJ/°C.

Zinc metal reacts with hydrochloric acid according to the balanced equation: Zn(s) + 2 HCl(aq) → ZnCl₂(aq) + H₂(g) When 0.103 g of Zn(s) is combined with enough HCl to make 50.0 mL of solution in a coffee-cup calorimeter, all of the zinc reacts, raising the temperature of the solution from 22.5 °C to 23.7 °C. Find ΔH_rxn for this reaction as written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g•°C as the specific heat capacity.)

Instant cold packs used to ice athletic injuries on the field contain ammonium nitrate and water separated by a thin plastic divider. When the divider is broken, the ammonium nitrate dissolves according to the endothermic reaction: NH₄NO₃(s) → NH₄⁺(aq) + NO₃^– (aq) In order to measure the enthalpy change for this reaction, 1.25 g of NH₄NO₃ is dissolved in enough water to make 25.0 mL of solution. The initial temperature is 25.8 °C and the final temperature (after the solid dissolves) is 21.9 °C. Calculate the change in enthalpy for the reaction in kJ. (Use 1.0 g/mL as the density of the solution and 4.18 J/g•°C as the specific heat capacity.)

For each generic reaction, determine the value of ΔH₂ in terms of ΔH₁.

a. A + B → 2 C ΔH₁

2 C→ A + B ΔH₂ = ?

For each generic reaction, determine the value of ΔH₂ in terms of ΔH₁.

b. A + 1/2 B → C ΔH₁

2 A + B → 2 C ΔH₂ = ?

For each generic reaction, determine the value of ΔH₂ in terms of ΔH₁.

c. A → B + 2 C ΔH₁

1/2 B + C → 1/2 A ΔH₂ = ?

Consider the generic reaction:

A + 2 B → C + 3 D ΔH = 155 kJ

Determine the value of ΔH for each related reaction.

a. 3 A + 6 B → 3 C + 9 D

b. C + 3 D → A + 2 B

c. 1/2 C + 3/2 D → 1/2 A + B

Calculate ΔH_rxn for the reaction:

Fe₂O₃(s) + 3 CO(g) → 2 Fe(s) + 3 CO₂(g)

Use the following reactions and given ΔH's:

2 Fe(s) + 3/2 O₂(g) → Fe₂O₃(s) ΔH = –824.2 kJ

CO(g) + 1/2 O₂(g) → CO₂(g) ΔH = –282.7 kJ

Calculate ΔHrxn for the reaction:

CaO(s) + CO₂(g) → CaCO₃(s)

Use the following reactions and given ΔH's:

Ca(s) + CO₂(g) + 1/2 O2(g) → CaCO₃(s) ΔH = –812.8 kJ

2 Ca(s) + O₂(g) → 2 CaO(s) ΔH = –1269.8 kJ

Calculate ΔHrxn for the reaction:

5 C(s) + 6 H₂(g) → C₅H₁₂(l)

Use the following reactions and given ΔH's:

C₅H₁₂(l) + 8 O₂(g) → 5 CO₂(g) + 6 H₂O(g) ΔH = –3244.8 kJ

C(s) + O₂(g) → CO₂(g) ΔH = –393.5 kJ

2 H₂(g) + O₂(g) → 2 H₂O(g) ΔH = –483.5 kJ

Calculate ΔHrxn for the reaction:

CH₄(g) + 4 Cl₂(g) → CCl₄(g) + 4 HCl(g)

Use the following reactions and given ΔH's:

C(s) + 2 H₂(g) → CH₄(g) ΔH = –74.6 kJ

C(s) + 2 Cl₂(g) → CCl₄( g) ΔH = –95.7 kJ

H₂(g) + Cl₂(g) → 2 HCl( g) ΔH = –92.3 kJ

Write an equation for the formation of each compound from its elements in their standard states, and find ΔH °f for each in Appendix IIB. a. NH₃(g)

Write an equation for the formation of each compound from its elements in their standard states, and find ΔH°_rxn for each in Appendix IIB. a. NO₂(g)

Write an equation for the formation of each compound from its elements in their standard states, and find ΔH°_rxn for each in Appendix IIB. b. MgCO₃(s)