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Ch.23 - Organic and Biological Chemistry
Chapter 23, Problem 55

Describe the structure of the functional group in each of the following families: (a) Alkene, (b) Alcohol, (c) Ester, (d) Amine.

Verified step by step guidance
1
Step 1: Understand that a functional group is a specific group of atoms within a molecule that is responsible for the characteristic chemical reactions of that molecule.
Step 2: For (a) Alkene, recognize that the functional group is a carbon-carbon double bond, denoted as C=C. This double bond is the site of reactivity in alkenes.
Step 3: For (b) Alcohol, identify the functional group as a hydroxyl group, represented by -OH. This group is bonded to a carbon atom and is responsible for the properties of alcohols.
Step 4: For (c) Ester, note that the functional group is characterized by the presence of a carbonyl group (C=O) adjacent to an ether linkage (O-C), typically written as RCOOR', where R and R' are hydrocarbon chains.
Step 5: For (d) Amine, recognize that the functional group consists of a nitrogen atom bonded to one or more alkyl or aryl groups, represented as -NH2, -NHR, or -NR2, where R is a hydrocarbon group.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Functional Groups

Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. They determine the properties and reactivity of organic compounds. Understanding functional groups is essential for predicting how different compounds will behave in chemical reactions.
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Carbonyl Functional Groups

Alkenes

Alkenes are hydrocarbons that contain at least one carbon-carbon double bond (C=C). This double bond is the functional group of alkenes, which influences their reactivity and physical properties. Alkenes are typically more reactive than alkanes due to the presence of this double bond, making them important in various chemical reactions, including polymerization.
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Rules for Naming Alkenes

Alcohols, Esters, and Amines

Alcohols contain a hydroxyl group (-OH) as their functional group, which makes them polar and capable of hydrogen bonding. Esters are characterized by a carbonyl group (C=O) adjacent to an ether group (–O–), giving them unique flavors and fragrances. Amines feature a nitrogen atom bonded to one or more alkyl or aryl groups, and their functional group (-NH2, -NHR, or -NR2) influences their basicity and solubility in water.
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Ester Reactions: Esterification