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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 14

State whether each of the following statements is true or false. Justify your answer in each case. (b) When ammonium nitrate, NH4NO3, dissolves in water, the solution is weakly conducting and basic in nature.

Verified step by step guidance
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Step 1: Identify the ions formed when ammonium nitrate (NH4NO3) dissolves in water. NH4NO3 dissociates into NH4+ (ammonium ion) and NO3- (nitrate ion).
Step 2: Analyze the nature of the ammonium ion (NH4+). NH4+ is the conjugate acid of NH3 (ammonia), which means it can donate a proton (H+) to water, making the solution slightly acidic.
Step 3: Analyze the nature of the nitrate ion (NO3-). NO3- is the conjugate base of a strong acid (HNO3), which means it does not significantly affect the pH of the solution.
Step 4: Consider the conductivity of the solution. Since NH4NO3 dissociates into ions, the solution will conduct electricity, but the extent of conductivity depends on the concentration of ions.
Step 5: Conclude the nature of the solution. Since NH4+ makes the solution slightly acidic and the solution is conducting due to the presence of ions, the statement that the solution is weakly conducting and basic is false.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Dissociation of Ionic Compounds

When ionic compounds like ammonium nitrate (NH4NO3) dissolve in water, they dissociate into their constituent ions (NH4+ and NO3-). This process allows the solution to conduct electricity due to the movement of these charged particles. Understanding this dissociation is crucial for evaluating the conductivity of the solution.
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Ionic Compounds Naming

Acid-Base Properties of Ions

The nature of the ions produced upon dissolution affects the acidity or basicity of the solution. Ammonium ion (NH4+) can act as a weak acid, while nitrate ion (NO3-) is neutral. The presence of NH4+ in solution can lead to a slightly acidic environment, contradicting the statement that the solution is basic.
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Arrhenius Acids and Bases

Electrical Conductivity in Solutions

The ability of a solution to conduct electricity depends on the concentration and mobility of ions present. While NH4NO3 does produce ions in solution, its conductivity is considered weak compared to strong electrolytes. This aspect is important for determining the overall conductivity of the solution when ammonium nitrate is dissolved in water.
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Related Practice
Textbook Question

In a titration experiment, 50.0 mL of 0.075 M acetic acid, CH3COOH, is titrated with the 0.250 M KOH(aq) that is in the burette. The drawing shows the level of the KOH in the burette before the titration begins. What will be the burette reading at the equivalence point?

Textbook Question

State whether each of the following statements is true or false. Justify your answer in each case. (a) Electrolyte solutions conduct electricity because electrons are moving through the solution.

Textbook Question

State whether each of the following statements is true or false. Justify your answer in each case. (b) If you add a nonelectrolyte to an aqueous solution that already contains an electrolyte, the electrical conductivity will not change.

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Textbook Question

We have learned in this chapter that many ionic solids dissolve in water as strong electrolytes; that is, as separated ions in solution. Which statement is most correct about this process? (a) Water is a strong acid and therefore is good at dissolving ionic solids. (b) Water is good at solvating ions because the hydrogen and oxygen atoms in water molecules bear partial charges. (c) The hydrogen and oxygen bonds of water are easily broken by ionic solids.

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Textbook Question

Would you expect that an anion would be physically closer to the oxygen or to the hydrogens of water molecules that surround it in solution?

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Textbook Question

Specify what ions are present in solution upon dissolving each of the following substances in water: a. FeCl2