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Multiple Choice
What is the pH of a solution after mixing 250 mL of 0.250 M HBr with 250 mL of 0.125 M NaOH?
A
1.00
B
7.00
C
13.00
D
2.00
Verified step by step guidance
1
First, identify the type of reaction occurring. HBr is a strong acid and NaOH is a strong base, so they will undergo a neutralization reaction: \( \text{HBr} + \text{NaOH} \rightarrow \text{NaBr} + \text{H}_2\text{O} \).
Calculate the moles of HBr and NaOH present in the solution. Use the formula \( \text{moles} = \text{concentration} \times \text{volume} \). For HBr: \( 0.250 \text{ M} \times 0.250 \text{ L} = 0.0625 \text{ moles} \). For NaOH: \( 0.125 \text{ M} \times 0.250 \text{ L} = 0.03125 \text{ moles} \).
Determine the limiting reactant by comparing the moles of HBr and NaOH. Since NaOH has fewer moles (0.03125 moles), it is the limiting reactant and will be completely consumed in the reaction.
Calculate the moles of HBr remaining after the reaction. Subtract the moles of NaOH from the initial moles of HBr: \( 0.0625 \text{ moles} - 0.03125 \text{ moles} = 0.03125 \text{ moles} \) of HBr remain.
Find the concentration of the remaining HBr in the final solution. The total volume of the solution after mixing is \( 250 \text{ mL} + 250 \text{ mL} = 500 \text{ mL} = 0.500 \text{ L} \). The concentration of HBr is \( \frac{0.03125 \text{ moles}}{0.500 \text{ L}} = 0.0625 \text{ M} \). Finally, calculate the pH using the formula \( \text{pH} = -\log[\text{H}^+] \), where \([\text{H}^+] = 0.0625 \text{ M}\).