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Multiple Choice
What is the pH of a solution made by mixing 0.30 mol of NaOH, 0.25 mol of Na2HPO4, and 0.20 mol of H3PO4 with water and diluting to 1.00 L?
A
pH = 7.0
B
pH = 1.0
C
pH = 3.0
D
pH = 13.0
Verified step by step guidance
1
Identify the species in the solution: NaOH is a strong base, Na2HPO4 is a salt that can act as a weak base, and H3PO4 is a weak acid.
Calculate the moles of OH⁻ ions contributed by NaOH. Since NaOH is a strong base, it dissociates completely in water, providing 0.30 mol of OH⁻ ions.
Consider the reaction between H3PO4 and OH⁻. H3PO4 can react with OH⁻ to form H2PO4⁻ and water. Calculate the moles of OH⁻ that will react with H3PO4.
Determine the remaining concentration of OH⁻ ions after the reaction with H3PO4. Subtract the moles of OH⁻ that reacted with H3PO4 from the initial moles of OH⁻.
Calculate the pOH of the solution using the concentration of remaining OH⁻ ions, and then convert pOH to pH using the relation: \( \text{pH} = 14 - \text{pOH} \).