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Multiple Choice
What is the standard enthalpy change of formation for NaCl(aq) at 25°C?
A
-411 kJ/mol
B
-425 kJ/mol
C
-418 kJ/mol
D
-407 kJ/mol
Verified step by step guidance
1
Understand that the standard enthalpy change of formation (ΔH_f°) is the change in enthalpy when one mole of a compound is formed from its elements in their standard states at 25°C and 1 atm.
Write the balanced chemical equation for the formation of NaCl(aq) from its elements in their standard states: Na(s) + 1/2 Cl2(g) → NaCl(aq).
Use Hess's Law, which states that the total enthalpy change for a reaction is the same, no matter how many steps the reaction is carried out in, to find the ΔH_f° for NaCl(aq).
Look up the standard enthalpy changes of formation for the reactants and products involved in the reaction. For Na(s) and Cl2(g), these values are typically zero because they are in their standard states.
Calculate the standard enthalpy change of formation for NaCl(aq) by using the formula: ΔH_f° = ΣΔH_f°(products) - ΣΔH_f°(reactants). Substitute the known values into this equation to find the ΔH_f° for NaCl(aq).