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Multiple Choice
The oxidation of ammonia is illustrated by the following equation: 4 NH3 (g) + 5 O2 (g) → 4 NO (g) + 6 H2O (g) Calculate the enthalpy of reaction,ΔHRxn, based on the given standard heats of formation.
A
-906 kJ
B
-1273.2 kJ
C
1089.6 kJ
D
-183.6 kJ
Verified step by step guidance
1
Identify the balanced chemical equation for the reaction: 4 NH3 (g) + 5 O2 (g) → 4 NO (g) + 6 H2O (g).
Use the standard heats of formation (ΔHf°) from the table: NH3 (g) = -45.9 kJ/mol, O2 (g) = 0.0 kJ/mol, NO (g) = 90.3 kJ/mol, H2O (g) = -241.8 kJ/mol.
Apply the formula for the enthalpy change of the reaction: ΔHRxn = Σ(ΔHf° of products) - Σ(ΔHf° of reactants).
Calculate the total ΔHf° for the products: (4 mol × 90.3 kJ/mol for NO) + (6 mol × -241.8 kJ/mol for H2O).
Calculate the total ΔHf° for the reactants: (4 mol × -45.9 kJ/mol for NH3) + (5 mol × 0.0 kJ/mol for O2) and subtract this from the total ΔHf° of the products to find ΔHRxn.