Which of the following is true about the general trend of first ionization energies in transition metals?

Two first-series transition metals have three unpaired electrons in complex ions of the type [MCl4]2-.

(a) What are the oxidation state and the identity of M in these complexes?

(b) Draw valence bond orbital diagrams for the two possible ions.

(c) Based on common oxidation states of first-series transition metals (Figure 21.6), which ion is more likely to exist?

<QUESTION REFERENCES FIGURE 21.6>

The highest oxidation state for the early transition metals Sc, Ti, V, Cr, and Mn is the periodic group number. The highest oxidation state for the later transition elements Fe, Co, and Ni is less than the periodic group number. Explain.

In which compound does Ti exhibit greater metallic behavior:TiF₂ or TiF₆?

Which oxide, CrO₃ or CrO, forms a more acidic aqueous solution?