Ch.21 - Transition Elements and Coordination Chemistry

McMurry8th EditionChemistryISBN: 9781292336145Not the one you use?Change textbook

McMurry 8th Edition

Ch.21 - Transition Elements and Coordination Chemistry

Problem 21.129a

Chapter 21, Problem 21.129a

Two first-series transition metals have three unpaired electrons in complex ions of the type [MCl4]2-.
(a) What are the oxidation state and the identity of M in these complexes?
(b) Draw valence bond orbital diagrams for the two possible ions.
(c) Based on common oxidation states of first-series transition metals (Figure 21.6), which ion is more likely to exist?
<QUESTION REFERENCES FIGURE 21.6>

Verified step by step guidance

Determine the oxidation state of M: The complex ion is [MCl_4]^{2-}. Each chloride ion (Cl^-) has a charge of -1. Therefore, the total charge contributed by the four chloride ions is -4. Since the overall charge of the complex is -2, the oxidation state of M must be +2 to balance the charges.

Identify the transition metals with three unpaired electrons in a +2 oxidation state: In the first transition series, the metals with three unpaired electrons in a +2 oxidation state are typically those with a d^7 electron configuration. These metals are Cobalt (Co) and Nickel (Ni).

Draw valence bond orbital diagrams: For each metal ion, draw the d-orbital splitting diagram in a tetrahedral field. Show the distribution of electrons in the d-orbitals, ensuring that there are three unpaired electrons.

Consider the common oxidation states: Refer to Figure 21.6 or a similar resource to determine which of the two metals, Co or Ni, is more commonly found in the +2 oxidation state.

Conclude which ion is more likely to exist: Based on the common oxidation states and the stability of the electron configuration, determine which of the two ions, [CoCl_4]^{2-} or [NiCl_4]^{2-}, is more likely to exist.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Oxidation States of Transition Metals

The oxidation state of a transition metal in a complex ion indicates the charge of the metal ion after accounting for the charges of the ligands. In the case of [MCl4]2-, the overall charge is -2, and since each chloride ion (Cl-) has a charge of -1, the oxidation state of M can be calculated by balancing these charges. Understanding oxidation states is crucial for identifying the metal and its possible electronic configurations.

Valence Bond Theory and Orbital Diagrams

Valence Bond Theory explains how atomic orbitals combine to form bonds in molecules. For transition metals, the d orbitals play a significant role in bonding and can be involved in hybridization. Drawing orbital diagrams for the complex ions helps visualize the arrangement of electrons, particularly the unpaired electrons, which are essential for determining the magnetic properties and reactivity of the complexes.

Common Oxidation States of First-Series Transition Metals

First-series transition metals exhibit a variety of oxidation states due to the involvement of d electrons in bonding. Common oxidation states can be predicted based on the electron configuration and the stability of the resulting ions. By referring to Figure 21.6, one can assess which oxidation states are more prevalent and likely to form stable complexes, aiding in the identification of the metal in the given complex.

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Related Practice

Textbook Question

There are two possible [M(OH)4]- complexes of first-series transition metals that have three unpaired electrons.

(a) What are the oxidation state and the identity of M in these complexes?

(b) Using orbital diagrams, give a valence bond description of the bonding in each complex.

(c) Based on common oxidation states of first-series transition metals (Figure 21.6), which [M(OH)4]- complex is more likely to exist?

<QUESTION REFERENCES FIGURE 21.6>-

Textbook Question

Tell how many diastereoisomers are possible for each of the following complexes, and draw their structures.

(a) Pt(NH₃)₃Cl (square planar)

(b) [FeBr₂Cl₂(en)]^-

Textbook Question

Assign a systematic name to each of the following ions.

(a) [AuCl₄]^-

(b) [Fe(CN)₆]^4-

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Textbook Question

Constitutional isomers of a ruthenium(II) coordination compound are shown below.

(a) Give the formula and name for structures 1-3.

(b) Which structures are linkage isomers?

Textbook Question

Look at the location in the periodic table of elements A, B, C, and D. What is the electron configuration of the transition metal in each of the following ions?

(a) A²⁺

(b) B⁺

Textbook Question

Give a valence bond description of the bonding in each of the following complexes. Include orbital diagrams for the free metal ion and the metal ion in the complex. Indicate which hybrid orbitals the metal ion uses for bonding, and specify the number of unpaired electrons.

(b) [NiBr₄]^2- (tetrahedral)