Organic Chemistry
4-nitrophenol has a significantly higher melting point because 2-nitrophenol has an activating group in the ortho position.
4-nitrophenol has a significantly higher melting point because it has a deactivating group in the para position.
4-nitrophenol has a significantly higher melting point because 2-nitrophenol has weaker intermolecular H-bonding.
4-nitrophenol has a significantly higher melting point because 2-nitrophenol has unstable resonance contributors.