Consider the reaction and the associated equilibrium constant: aA(g) ⇌ bB(g) Kc = 4.0 Find the equilibrium concentrations of A and B for each value of a and b. Assume that the initial concentration of A in each case is 1.0 M and that no B is present at the beginning of the reaction. c. a=1;b=2

For the reaction shown here, K_c = 0.513 at 500 K. N₂O₄(g) ⇌ 2 NO₂(g) If a reaction vessel initially contains an N₂O₄ concentration of 0.0500 M at 500 K, what are the equilibrium concentrations of N₂O₄ and NO₂ at 500 K?

For the reaction shown here, K_c = 255 at 1000 K. CO(g) + Cl₂(g) ⇌ COCl₂(g) If a reaction mixture initially contains a CO concentration of 0.1500 M and a Cl₂ concentration of 0.175 M at 1000 K, what are the equilibrium concentrations of CO, Cl₂, and COCl₂ at 1000 K?

Consider the reaction: HC₂H₃O₂(aq) + H₂O(l) ⇌ H₃O⁺(aq) + C₂H₃O₂^-(aq) K_c = 1.8⨉10^-5 at 25°C If a solution initially contains 0.210 M HC₂H₃O₂, what is the equilibrium concentration of H₃O⁺ at 25 °C?

Consider the reaction: SO₂Cl₂(g) ⇌ SO₂(g) + Cl₂(g) K_c = 2.99⨉10^-7 at 227 °C If a reaction mixture initially contains 0.175 M SO₂Cl₂, what is the equilibrium concentration of Cl₂ at 227 °C?

Consider the reaction: A(g) ⇌ B(g) + C(g) Find the equilibrium concentrations of A, B, and C for each value of K_c. Assume that the initial concentration of A in each case is 1.0 M and that the reaction mixture initially contains no products. Make any appropriate simplifying assumptions. b. K_c = 0.010

Consider this reaction at equilibrium: 2 BrNO(g) ⇌ 2 NO(g) + Br₂(g) Predict whether the reaction will shift left, shift right, or remain unchanged after each disturbance. a. NO is added to the reaction mixture.

Consider this reaction at equilibrium: 2 BrNO(g) ⇌ 2 NO(g) + Br₂(g) Predict whether the reaction will shift left, shift right, or remain unchanged after each disturbance. b. BrNO is added to the reaction mixture.

Consider this reaction at equilibrium: 2 BrNO(g) ⇌ 2 NO(g) + Br₂(g) Predict whether the reaction will shift left, shift right, or remain unchanged after each disturbance. c. Br₂ is removed from the reaction mixture.

Consider this reaction at equilibrium:

C(s) + H2O(g) ⇌ CO(g) + H2(g)

Predict whether the reaction will shift left, shift right, or remain unchanged after each disturbance.

a. C is removed from the reaction mixture.

Each reaction is allowed to come to equilibrium, and then the volume is changed as indicated. Predict the effect (shift right, shift left, or no effect) of the indicated volume change. a. I₂( g) ⇌ 2 I( g) (volume is increased) b. 2 H₂S( g) ⇌ 2 H₂( g) + S₂(g) (volume is decreased) c. I₂(g) + Cl₂(g) ⇌ 2 ICl(g) (volume is decreased)

Each reaction is allowed to come to equilibrium, and then the volume is changed as indicated. Predict the effect (shift right, shift left, or no effect) of the indicated volume change. a. CO(g) + H₂O( g) ⇌ CO₂(g) + H₂(g) (volume is decreased)

Each reaction is allowed to come to equilibrium, and then the volume is changed as indicated. Predict the effect (shift right, shift left, or no effect) of the indicated volume change. b. PCl₃(g) + Cl₂(g) ⇌ PCl₅(g) (volume is increased)

Each reaction is allowed to come to equilibrium, and then the volume is changed as indicated. Predict the effect (shift right, shift left, or no effect) of the indicated volume change. c. CaCO₃(s) ⇌ CaO(s) + CO₂(g) (volume is increased)

This reaction is endothermic. C(s) + CO₂(g) ⇌ 2 CO(g) Predict the effect (shift right, shift left, or no effect) of increasing and decreasing the reaction temperature. How does the value of the equilibrium constant depend on temperature?

Coal, which is primarily carbon, can be converted to natural gas, primarily CH₄, by the exothermic reaction: C(s) + 2 H₂(g) ⇌ CH₄(g) Which disturbance will favor CH₄ at equilibrium?

a. adding more C to the reaction mixture b. adding more H₂ to the reaction mixture d. lowering the volume of the reaction mixture f. adding neon gas to the reaction mixture

Coal, which is primarily carbon, can be converted to natural gas, primarily CH₄, by the exothermic reaction: C(s) + 2 H₂(g) ⇌ CH₄(g) Which disturbance will favor CH₄ at equilibrium? c. raising the temperature of the reaction mixture

Coal, which is primarily carbon, can be converted to natural gas, primarily CH₄, by the exothermic reaction: C(s) + 2 H₂(g) ⇌ CH₄(g) Which disturbance will favor CH₄ at equilibrium? e. adding a catalyst to the reaction mixture

Coal can be used to generate hydrogen gas (a potential fuel) by the endothermic reaction: C(s) + H₂O(g) ⇌ CO(g) + H₂(g) If this reaction mixture is at equilibrium, predict whether each disturbance will result in the formation of additional hydrogen gas, the formation of less hydrogen gas, or have no effect on the quantity of hydrogen gas. e. adding a catalyst to the reaction mixture

Carbon monoxide replaces oxygen in oxygenated hemoglobin according to the reaction: HbO₂(aq) + CO(aq) ⇌ HbCO(aq) + O₂(aq) a. Use the reactions and associated equilibrium constants at body temperature given here to find the equilibrium constant for the reaction just shown. Hb(aq) + O₂(aq) ⇌ HbO₂(aq) K_c = 1.8 Hb(aq) + CO(aq) ⇌ HbCO(aq) K_c = 306

At 650 K, the reaction MgCO₃(s) ⇌ MgO(s) + CO₂(g) has K_p = 0.026. A 10.0-L container at 650 K has 1.0 g of MgO(s) and CO₂ at P = 0.0260 atm. The container is then compressed to a volume of 0.100 L. Find the mass of MgCO₃ that is formed.

Consider the exothermic reaction: C₂H₄(g) + Cl₂(g) ⇌ C₂H₄Cl₂(g) If you were trying to maximize the amount of C₂H₄Cl₂ produced, which tactic might you try? Assume that the reaction mixture reaches equilibrium. a. increasing the reaction volume b. removing C₂H₄Cl₂ from the reaction mixture as it forms c. lowering the reaction temperature d. adding Cl₂

Consider the endothermic reaction: C₂H₄(g) + I₂(g) ⇌ C₂H₄I₂(g) If you were trying to maximize the amount of C₂H₄I₂ produced, which tactic might you try? Assume that the reaction mixture reaches equilibrium. a. decreasing the reaction volume b. removing I₂ from the reaction mixture c. raising the reaction temperature d. adding C₂H₄ to the reaction mixture