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Ch.17 - Aqueous Ionic Equilibrium
Chapter 17, Problem 12

A 0.5224-g sample of an unknown monoprotic acid was titrated with 0.0998 M NaOH. The equivalence point of the titration occurred at 23.82 mL. Determine the molar mass of the unknown acid.

Verified step by step guidance
1
Identify that the problem involves a titration of a monoprotic acid with NaOH, where the equivalence point is reached when moles of acid equal moles of base.
Use the formula for moles of NaOH: \( \text{moles of NaOH} = M \times V \), where \( M \) is the molarity (0.0998 M) and \( V \) is the volume in liters (23.82 mL converted to liters).
Since the acid is monoprotic, the moles of acid will be equal to the moles of NaOH at the equivalence point.
Calculate the molar mass of the unknown acid using the formula: \( \text{Molar mass} = \frac{\text{mass of acid}}{\text{moles of acid}} \), where the mass of the acid is 0.5224 g.
Substitute the values obtained from the previous steps into the molar mass formula to find the molar mass of the unknown acid.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Titration

Titration is a quantitative analytical technique used to determine the concentration of a solute in a solution. In this process, a solution of known concentration (the titrant) is gradually added to a solution of unknown concentration until the reaction reaches its equivalence point, where stoichiometrically equivalent amounts of reactants have reacted. This technique is commonly used in acid-base reactions to find the concentration of an acid or base.
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Equivalence Point

The equivalence point in a titration is the stage at which the amount of titrant added is stoichiometrically equivalent to the amount of substance in the sample being analyzed. For a monoprotic acid titrated with a strong base like NaOH, this point indicates that all the acid has reacted with the base. It is crucial for calculating the molar mass of the acid, as it provides the volume of base required to neutralize the acid.
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Molar Mass Calculation

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). To calculate the molar mass of the unknown acid in this titration scenario, one must use the mass of the acid sample and the number of moles of acid that reacted, which can be determined from the volume and concentration of the NaOH used at the equivalence point. This relationship allows for the determination of the molar mass based on the formula: Molar Mass = mass of acid / moles of acid.
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Molar Mass Calculation Example