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Ch.6 - Ionic Compounds: Periodic Trends and Bonding Theory
Chapter 6, Problem 57

Which element in the periodic table has the smallest ionization energy? Which element has the largest ionization energy?

Verified step by step guidance
1
Step 1: Understand the concept of ionization energy, which is the energy required to remove an electron from an atom in the gaseous state.
Step 2: Recall the periodic trend for ionization energy: it generally increases across a period (from left to right) and decreases down a group (from top to bottom) in the periodic table.
Step 3: Identify the element with the smallest ionization energy. This is typically found at the bottom of Group 1 (alkali metals), as these elements have the least attraction between the nucleus and the outermost electron.
Step 4: Identify the element with the largest ionization energy. This is typically found at the top of Group 18 (noble gases), as these elements have a full valence shell and a strong attraction between the nucleus and the outermost electrons.
Step 5: Consider exceptions and specific elements: While the general trend helps, specific elements like Helium (He) have the highest ionization energy due to their small size and full valence shell, and Francium (Fr) has the lowest due to its large size and single valence electron.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ionization Energy

Ionization energy is the amount of energy required to remove an electron from an atom in its gaseous state. It is a key property that reflects how strongly an atom holds onto its electrons. Generally, ionization energy increases across a period from left to right due to increasing nuclear charge and decreases down a group as the distance between the nucleus and the outermost electrons increases.
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Periodic Trends

Periodic trends refer to the predictable patterns observed in the properties of elements as you move across or down the periodic table. For ionization energy, the trend shows that elements on the right side of the table (like noble gases) tend to have higher ionization energies, while those on the left (like alkali metals) have lower ionization energies. Understanding these trends helps in predicting the behavior of elements.
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Noble Gases and Alkali Metals

Noble gases, located in Group 18 of the periodic table, have the highest ionization energies due to their full valence electron shells, making them stable and less likely to lose electrons. In contrast, alkali metals, found in Group 1, have the lowest ionization energies because they have a single electron in their outer shell, which is easily removed. This distinction is crucial for identifying the elements with the smallest and largest ionization energies.
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