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- Silver metal reacts with chlorine (Cl2) to yield silver chlo-ride. If 2.00 g of Ag reacts with 0.657 g of Cl2, what is the empirical formula of silver chloride?
Problem 68
- Aluminum reacts with oxygen to yield aluminum oxide. If 5.0 g of Al reacts with 4.45 g of O2, what is the empirical formula of aluminum oxide?
Problem 69
- The industrial production of hydriodic acid takes place by treatment of iodine with hydrazine (N2H4): 2 I2 + N2H4 --> 4 HI + N2 (b) How many grams of HI are produced from the reaction of 115.7 g of N2H4 with excess iodine
Problem 70
Problem 71a
An alternative method for producing hydriodic acid is the reaction of iodine with hydrogen sulfide: H2S + I2 → 2 HI + S (a) How many grams of I2 are needed to react with 49.2 g of H2S?
Problem 71b
An alternative method for producing hydriodic acid is the reaction of iodine with hydrogen sulfide:H2S + I2 → 2 HI + S (b) How many grams of HI are produced from the reaction of 95.4 g of H2S with excess I2?
Problem 72a
Nickel(II) sulfate, used for nickel plating, is prepared by treat-ment of nickel(II) carbonate with sulfuric acid: NiCO3 + H2SO4 → NiSO4 + CO2 + H2O (a) How many grams of H2SO4 are needed to react with 14.5 g of NiCO3?
Problem 72b
Nickel(II) sulfate, used for nickel plating, is prepared by treat-ment of nickel(II) carbonate with sulfuric acid: NiCO3 + H2SO4 → NiSO4 + CO2 + H2O
(b) How many grams of NiSO4 are obtained if the yield is 78.9%?
Problem 73a
Hydrazine, N2H4, once used as a rocket propellant, reacts with oxygen: N2H4 + O2 → N2 + 2 H2O (a) How many grams of O2 are needed to react with 50.0 g of N2H4?
Problem 73b
Hydrazine, N2H4, once used as a rocket propellant, reacts with oxygen: N2H4 + O2 → N2 + 2 H2O (b) How many grams of N2 are obtained if the yield is 85.5%?
- Assume that you have 1.39 mol of H2 and 3.44 mol of N2. How many grams of ammonia (NH3) can you make, and how many grams of which reactant will be left over? 3 H2 + N2 --> NH3
Problem 74
- Hydrogen and chlorine react to yield hydrogen chloride: H2 + Cl2 ¡ 2 HCl. How many grams of HCl are formed from reaction of 3.56 g of H2 with 8.94 g of Cl2? Which reactant is limiting?
Problem 75
Problem 76
How many grams of the dry-cleaning solvent 1,2-dichloroethane (also called ethylene chloride), C2H4Cl2, can be prepared by reaction of 15.4 g of ethylene, C2H4, with 3.74 g of Cl2?
Problem 77a
How many grams of each product result from the following reactions, and how many grams of which reactant is left over? (a)
Problem 77b
How many grams of each product result from the following reactions, and how many grams of which reactant is left over? (b)
Problem 78
Limestone (CaCO3) reacts with hydrochloric acid according to the equation CaCO3 + 2 HCl ---> CaCl2 + H2O + CO2. If 1.00 mol of CO2 has a volume of 22.4 L under the reaction conditions, how many liters of gas can be formed by reaction of 2.35 g of CaCO3 with 2.35 g of HCl? Which reactant is limiting?
- Sodium azide (NaN3) yields N2 gas when heated to 300 °C, a reaction used in automobile air bags. If 1.00 mol of N2 has a volume of 47.0 L under the reaction conditions, how many liters of gas can be formed by heating 38.5 g of NaN3? The reaction is
Problem 79
- Acetic acid (CH3CO2H) reacts with isopentyl alcohol (C5H12O) to yield isopentyl acetate (C7H14O2), a fragrant substance with the odor of bananas. If the yield from the reaction of acetic acid with isopentyl alcohol is 45%, how many grams of isopentyl acetate are formed from 3.58 g of acetic acid and 4.75 g of isopentyl alcohol? The reaction is CH3CO2H + C5H12O ---> C7H14O2 + H2O
Problem 80
- Cisplatin [Pt(NH3)2Cl2], a compound used in cancer treat-ment, is prepared by reaction of ammonia with potassium tetrachloroplatinate: K2PtCl4 + 2 NH3 ----> 2 KCl + Pt(NH3)2Cl2 How many grams of cisplatin are formed from 55.8 g of K2PtCl4 and 35.6 g of NH3 if the reaction takes place in 95% yield based on the limiting reactant?
Problem 81
- If 1.87 g of acetic acid (CH3COOH) reacts with 2.31 g of isopentyl alcohol (C5H12O) to give 2.96 g of isopentyl acetate (C7H14O2), what is the percent yield of the reaction?
Problem 82
- If 3.42 g of K2PtCl4 and 1.61 g of NH3 give 2.08 g of cispla-tin (Problem 3.81), what is the percent yield of the reaction?
Problem 83
Problem 84a
The reaction of tungsten hexachloride (WCl6) with bismuth gives hexatungsten dodecachloride (W6Cl12).
WCl6 + Bi → W6Cl12 + BiCl3 Unbalanced
(a) Balance the equation.
Problem 84b
The reaction of tungsten hexachloride (WCl6) with bismuth gives hexatungsten dodecachloride (W6Cl12).
WCl6 + Bi → W6Cl12 + BiCl3 Unbalanced
(b) How many grams of bismuth react with 150.0 g of WCl6?
Problem 84c
The reaction of tungsten hexachloride (WCl6) with bismuth gives hexatungsten dodecachloride (W6Cl12).
WCl6 + Bi → W6Cl12 + BiCl3 Unbalanced
(c) When 228 g of WCl6 react with 175 g of Bi, how much W6Cl12 is formed based on the limiting reactant?
Problem 85a
Sodium borohydride, NaBH4, a substance used in the synthesis of many pharmaceutical agents, can be prepared by reaction of NaH with B2H6 according to the equation 2 NaH + B2H6 → 2 NaBH4
(a) How many grams of NaBH4 can be prepared by reaction between 8.55 g of NaH and 6.75 g of B2H6?
Problem 85b
Sodium borohydride, NaBH4, a substance used in the synthesis of many pharmaceutical agents, can be prepared by reaction of NaH with B2H6 according to the equation 2 NaH + B2H6 → 2 NaBH4
(b) Which reactant is limiting, and how many grams of the excess reactant will be left over?
- Urea, a substance commonly used as a fertilizer, has the for-mula CH4N2O. What is its percent composition by mass?
Problem 86
Problem 87a
Calculate the mass percent composition of each of the following substances. (a) Malachite, a copper-containing mineral: Cu2(OH)2CO3
Problem 87b
Calculate the mass percent composition of each of the following substances. (b) Acetaminophen, a headache remedy: C8H9NO2
Problem 87c
Calculate the mass percent composition of each of the following substances. (c) Prussian blue, an ink pigment: Fe4[Fe(CN)6]3
Problem 88a
What are the empirical formulas of substances with the following mass percent compositions? (a) Aspirin: 4.48% H, 60.00% C, 35.52% O